Multilayer OLED Encapsulation Barrier and Planarization

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Solution Overview

Problem

Existing encapsulation methods for optoelectronic components, particularly OLEDs, fail to provide adequate protection against water and oxygen degradation, which is critical for automotive applications due to high water vapor and oxygen permeability.

Innovation Solution

A multilayer encapsulation comprising a barrier layer and a planarization layer, where the planarization layer enhances the barrier properties, reducing water and oxygen permeability, and is applied using inorganic materials like metal oxides and vitreous materials, ensuring low permeability and flexibility for both rigid and flexible OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single barrier layer is used for encapsulation, then the structure is simple, but the water and oxygen permeability is too high for automotive applications

Engineering Contradiction:
Improveprotection against water and oxygen degradationVSAvoidencapsulation structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs a composite multilayer encapsulation structure consisting of alternating organic and inorganic layers. The organic layers (e.g., acrylic resins, epoxies) provide flexibility, adhesion, and planarization, while the inorganic barrier layers (e.g., metal oxides like alumina, zirconium oxide, or silicon oxide) provide exceptional water and oxygen barrier properties. This composite approach achieves the required low permeability for automotive applications while maintaining structural integrity and flexibility.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The encapsulation is divided into multiple discrete layers with specific functions. The barrier layers are segmented into multiple thin inorganic sub-layers separated by organic interlayers, creating a nanolaminate structure. This segmentation allows each layer to perform its specific function optimally - the inorganic layers block water and oxygen molecules, while the organic layers provide mechanical flexibility and adhesion between barrier layers.

Inventive Principle:
Principle #1Segmentation

2Reliability

If inorganic barrier layers are applied to achieve low permeability, then water and oxygen protection is improved, but the encapsulation becomes rigid and unsuitable for flexible OLEDs

Engineering Contradiction:
Improvewater and oxygen barrier performanceVSAvoidflexibility for rigid and flexible OLEDs
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent utilizes thin organic film layers (50-500 nm thickness) between the inorganic barrier layers to introduce flexibility. These organic interlayers act as flexible spacers that allow the overall encapsulation structure to bend without cracking the brittle inorganic layers. The thin film nature maintains barrier effectiveness while the organic material composition provides the necessary flexibility for both rigid and flexible OLED applications.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The composite structure combines brittle inorganic barrier materials with flexible organic matrix materials. The inorganic layers (such as alumina, zirconium oxide) provide the barrier function, while the organic layers (acrylic resins, epoxies, polyimides) provide flexibility and mechanical compliance. This material combination enables the encapsulation to maintain its protective barrier function while adapting to both rigid and flexible substrate requirements.

Inventive Principle:
Principle #40Composite materials

3Reliability

If multiple barrier layers are stacked to reduce permeability, then water vapor transition rate decreases, but manufacturing complexity and process time increase

Engineering Contradiction:
Improvewater vapor transition rateVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent optimizes the thickness parameters of individual layers to achieve the required barrier performance with a minimal number of layers. By carefully controlling the thickness of organic interlayers (50-500 nm) and inorganic barrier layers (10-300 nm), the patent achieves low water vapor transmission rates without requiring excessive stacking. The parameter optimization balances barrier effectiveness with manufacturing efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Rather than using fewer thick barrier layers, the patent segments the barrier function into multiple thin inorganic sub-layers separated by organic interlayers. This segmentation creates a tortuous path for water and oxygen molecules, significantly enhancing barrier performance. The segmented structure achieves superior WVTR values while maintaining reasonable manufacturing complexity through standardized thin-film deposition processes.

Inventive Principle:
Principle #1Segmentation

4Manufacturing precision

If the planarization layer is made thicker to improve surface flatness, then surface quality improves, but water permeability increases

Engineering Contradiction:
Improvesurface flatnessVSAvoidwater permeability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The planarization function is achieved through organic layers with inherent planarization properties (such as spin-coated acrylic or epoxy resins) rather than relying solely on thickness. These organic planarization layers are then combined with inorganic barrier layers to create a composite structure where the organic component provides surface flatness and the inorganic component provides water vapor barrier performance, eliminating the trade-off between thickness and permeability.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multilayer encapsulation effectively protects OLEDs from water and oxygen degradation, achieving a water vapor transition rate of less than 10^-6 g/dm2 and oxygen permeability of less than 10^-6 cm3/m2d, ensuring reliable performance in automotive use while being flexible and transparent.

Implementation Method 1

the barrier layer and the planarization layer together have a lower water permeability than the barrier layer

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

the planarization layer in combination with the barrier layer can have an oxygen permeability of less than or equal to 10^-6 cm3/m2d

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS11569479B2Multilayer encapsulation, method for encapsulating and optoelectronic component
Publication Date: 2023.01.31 AMS OSRAM INT GMBH
  • US11569479B2 patent drawing
  • US11569479B2 patent drawing
  • US11569479B2 patent drawing

AI summary

A multilayer encapsulation, a method for encapsulating and an optoelectronic component are disclosed. In an embodiment an optoelectronic component includes a first electrode layer, an organic light-emitting layer stack abutting the first electrode layer, a second electrode layer abutting the light-emitting layer stack and a multilayer encapsulation abutting the second electrode layer, wherein the multilayer encapsulation comprises a barrier layer and a planarization layer, wherein the planarization layer abuts the second electrode layer, and wherein the planarization layer is arranged between the second electrode layer and the barrier layer.