OLED Organic Compound Dopant for Efficiency and Voltage Reduction

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Solution Overview

Problem

Organic light emitting diodes (OLEDs) face issues with luminous efficiency, high driving voltages, and power consumption, as well as short luminous lifetime and poor color purity due to the limitations of current luminous materials.

Innovation Solution

An organic compound with a specific structure, such as Chemical Formula 1, is used as a dopant in the emitting material layer of OLEDs, enhancing luminous efficiency and color purity by limiting triplet exciton energy transfer and utilizing singlet exciton energy through FRET mechanism, while reducing driving voltage and power consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional luminous materials are used in OLEDs, then the device can be manufactured with current technology, but the luminous efficiency is insufficient and power consumption is high

Engineering Contradiction:
Improveluminous efficiencyVSAvoidpower consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent changes the molecular structure parameters of the luminous material by introducing specific substituents (R1-R6 groups) at defined positions on the core structure. This modifies the energy levels and electronic properties of the material, enabling more efficient singlet exciton utilization and reduced triplet exciton energy transfer, thereby improving luminous efficiency and reducing power consumption

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite molecular structure combining a core structure with multiple substituent groups (aromatic, hetero aromatic, alkyl, alkoxy groups). This composite structure integrates different functional groups that work synergistically to enhance charge transport, improve exciton management, and optimize optical properties for higher efficiency and lower power consumption

Inventive Principle:
Principle #40Composite materials

2Power

If conventional luminous materials are used in OLEDs, then the device structure can be maintained, but the driving voltage is relatively high

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice structure
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent modifies the HOMO and LUMO energy level parameters of the luminous material through strategic substituent placement. This energy level optimization facilitates better charge injection and transport, reducing the driving voltage required for OLED operation while maintaining the overall device structure

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If conventional luminous materials are used in OLEDs, then the manufacturing process can be kept simple, but the color purity is poor

Engineering Contradiction:
Improvecolor purityVSAvoidmanufacturing process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent applies local quality by introducing specific substituents at defined positions (R1-R6) on the core structure. Each substituent location contributes to specific optical properties, allowing precise control over emission wavelength and color purity. This localized structural modification enables high color purity without complicating the overall manufacturing process

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the optical parameters of the luminous material by modifying the molecular structure with specific aromatic and hetero aromatic groups. These structural changes shift the emission spectrum and narrow the full width at half maximum (FWHM), thereby improving color purity while maintaining compatibility with existing manufacturing processes

Inventive Principle:
Principle #35Parameter changes

4Duration of action of stationary object

If conventional luminous materials are used in OLEDs, then the device can operate, but the luminous lifetime is short

Engineering Contradiction:
Improveluminous lifetimeVSAvoidmaterial stability
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent optimizes the molecular stability parameters by incorporating robust aromatic and hetero aromatic substituents that resist degradation. The structural design enhances chemical stability and reduces photo-oxidation, extending the luminous lifetime and improving the reliability of the OLED device

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound improves the luminous efficiency and lifetime of OLEDs by increasing the utilization of singlet exciton energy, enhancing color purity, and reducing power consumption, making OLEDs more efficient and effective.

Implementation Method 1

utilizing singlet exciton energy through FRET mechanism

Methodology Applied
Scientific EffectFRET mechanism:

Data Source

PatentUS11820761B2Organic compound, organic light emitting diode and organic light emitting device including the organic compound
Publication Date: 2023.11.21 LG DISPLAY CO LTD
  • US11820761B2 patent drawing
  • US11820761B2 patent drawing
  • US11820761B2 patent drawing

AI summary

The present disclosure relates to an organic compound having the following structure, and an organic light emitting diode (OLED) and an organic light emitting device including the organic compound. Applying the organic compound into an emissive layer makes the OLED and the organic light emitting device lower their driving voltage, improves their luminous efficiency and color purity.