OLED Color Conversion with Quantum Dots

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Solution Overview

Problem

Existing color conversion layers in OLEDs incorporate sensitive materials that reduce the lifetime and luminous intensity of the components, and cause undesirable color variations due to differential aging, making them unsuitable for stable lighting applications.

Innovation Solution

Incorporating quantum dots in a color conversion layer, which are inorganic, photochemically stable, and have a wider absorption band, allowing for a stable emission wavelength and easier processing to achieve a desired emission spectrum approximated to white light, thereby enhancing the longevity and color consistency of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If color conversion layers with colorants and polymer matrix are used in OLEDs, then the desired light color or white light can be generated, but the lifetime of the components is reduced and luminous intensity decreases due to decomposition of organic constituents

Engineering Contradiction:
Improvelight color qualityVSAvoidcomponent lifetime
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent changes the material parameters of the color conversion layer by replacing organic colorants with inorganic quantum dots. This fundamental material substitution eliminates the decomposition issue while maintaining the color conversion function, thereby resolving the contradiction between light quality and component lifetime.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining quantum dots with a polymer matrix or using quantum dots as a suspension. This composite approach allows the color conversion layer to maintain structural integrity and optical performance while the inorganic quantum dots provide enhanced stability and longevity compared to pure organic materials.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If multiple color conversion layers with different colorants are combined to approximate daylight, then the desired white light spectrum is achieved, but color variation occurs prematurely due to different aging rates of the color conversion layers

Engineering Contradiction:
Improvewhite light spectrum qualityVSAvoidcolor consistency
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent changes the material composition from organic colorants to inorganic quantum dots, which have fundamentally different aging characteristics. Quantum dots exhibit superior chemical stability and resistance to environmental degradation, ensuring that multiple quantum dot layers maintain consistent emission properties over time, thereby resolving the color consistency issue.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent promotes homogeneity by using quantum dots with uniform size distributions and compositions. This ensures that all quantum dot layers age at similar rates and maintain consistent optical properties, eliminating the differential aging problem that occurs with heterogeneous organic colorant materials.

Inventive Principle:
Principle #33Homogeneity

3Reliability

If quantum dots are used in the color conversion layer, then photochemical stability and emission wavelength consistency are improved, but additional processing steps are required for dispersion and integration

Engineering Contradiction:
Improveemission stabilityVSAvoidprocessing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses a polymer matrix or suspension medium as an intermediary to facilitate the integration of quantum dots into the OLED structure. This intermediary simplifies the manufacturing process by providing a ready-to-use dispersion medium that can be applied using standard coating techniques, thereby reducing processing complexity while maintaining emission stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Device complexity

If the color conversion layer is applied directly on the layer construction, then the structure is simplified, but the quantum dots may be damaged during layer application processes

Engineering Contradiction:
Improvelayer structureVSAvoidquantum dot integrity
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent applies preliminary protective action by encapsulating quantum dots in a polymer matrix or suspension before integration into the OLED. This pre-protection ensures that the quantum dots are already shielded when subjected to subsequent layer application processes, preventing damage while maintaining structural simplicity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of quantum dots in OLEDs results in a longer-lasting and more stable light emission with improved color consistency, suitable for lighting purposes, as they absorb blue radiation effectively and maintain emission stability without aging, allowing for scalable and flexible OLED designs.

Implementation Method 1

quantum dots present as nanoparticles or as a suspension of nanoparticles to be used directly for the layer production of the color conversion layer... absorb the primary radiation of the LED and to generate a longer-wave secondary radiation

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 2

They have the further advantage over color conversion layers with colorants that they have a significantly wider absorption band with respect to primary radiation and absorb practically all shorter-wave radiation lying in the range of blue OLEDs

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS8174034B2OLED with color conversion
Publication Date: 2012.05.08 AMS OSRAM INT GMBH
  • US8174034B2 patent drawing
  • US8174034B2 patent drawing
  • US8174034B2 patent drawing

AI summary

An OLED is thus specified which includes a layer construction comprising at least an anode, a cathode and a functional layer arranged in between, the layer construction being arranged on a substrate. At least one electrode, selected from the anode and cathode, is transmissive to the light emitted by the functional layer and is arranged on the light-emitting side, emission side, of the layer construction. The at least one color conversion layer has quantum dots and is arranged on the emission side above or below the layer construction.