OLED Optical Resonator Photolithographic Structuring

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Solution Overview

Problem

Existing methods for producing organic light-emitting diodes (OLEDs) face challenges in achieving precise alignment of shadow masks and multiple deposition steps, leading to complex and inefficient processes for generating full-color displays or light sources, with issues such as dust generation and insufficient color saturation and power efficiency.

Innovation Solution

A photolithographic process using a lossy optical resonator with a photochemically crosslinkable emitter layer and hole conductor layer of varying thicknesses, structured with a grayscale mask to achieve different optical path lengths and colors in a single step, allowing for the generation of a wide range of colors without the need for multiple alignments.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If shadow masks are used for multiple deposition steps to produce full-color OLEDs, then color variety is achieved, but process complexity and alignment difficulty increase significantly

Engineering Contradiction:
Improvecolor varietyVSAvoidprocess complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent combines multiple deposition steps into a single step by using a single layer containing multiple dyes with different emission colors. Instead of depositing separate layers for red, green, and blue colors using multiple shadow masks, the invention incorporates all color-emitting dyes into one emitter layer that can be deposited in a single vacuum deposition process, thereby eliminating the need for multiple alignment operations.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent segments the emission spectrum by incorporating different dyes at specific positions within the emitter layer. By strategically placing dyes with different emission wavelengths at different locations or depths within the same layer, the invention achieves full-color emission without requiring multiple physical layers or masks, thus simplifying the overall device structure while maintaining color versatility.

Inventive Principle:
Principle #1Segmentation

2Adaptability or versatility

If multiple shadow mask alignment steps are performed, then full-color display capability is achieved, but manufacturing precision requirements become extremely stringent

Engineering Contradiction:
Improvefull-color display capabilityVSAvoidalignment precision
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The invention merges the function of multiple shadow masks into a single deposition process. By incorporating multiple dyes into one emitter layer that is deposited in a single step, the need for multiple precise alignment operations is eliminated, thereby dramatically reducing the manufacturing precision requirements while still achieving full-color display capability.

Inventive Principle:
Principle #5Merging (Combining)

3Illumination intensity

If multiple deposition steps with shadow masks are used, then color saturation can be optimized, but dust generation and process inefficiency increase

Engineering Contradiction:
Improvecolor saturationVSAvoiddust generation
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

The patent combines multiple dye materials into a single deposition step, creating one emitter layer that contains all necessary color-emitting components. This approach eliminates the repeated opening and closing of vacuum chambers and the repeated insertion/removal of shadow masks, thereby reducing dust generation from the environment while maintaining color saturation through optimized dye placement and concentration within the single layer.

Inventive Principle:
Principle #5Merging (Combining)

4Measurement precision

If separate layers with different thicknesses are deposited to achieve different colors, then color accuracy is improved, but the number of deposition steps and overall process time increase

Engineering Contradiction:
Improvecolor accuracyVSAvoidprocess time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent segments the emitter layer into different regions or depth zones, each containing dyes with specific emission characteristics. By controlling the spatial distribution and concentration of different dyes within a single layer deposited in one step, the invention achieves precise color accuracy without requiring multiple sequential deposition steps, thereby significantly reducing the overall process time.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention merges the functionality of multiple separately deposited layers into a single composite emitter layer. This single layer contains multiple dyes positioned and concentrated to achieve the desired color accuracy, eliminating the need for multiple deposition steps and reducing the total process time while maintaining or improving color precision.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the production of OLEDs by enabling the generation of various colors in a single work step, improving color accuracy and efficiency, and allowing for the creation of displays and light sources with enhanced color rendering and reduced complexity, suitable for both display and sensor technology applications.

Implementation Method 1

an optical resonator consisting of two reflective layers 2, 7 for reflecting light, in which a standing wave forms if the optical path length of the resonator is a multiple of the wavelength of the emitted light

Methodology Applied
Scientific EffectOptical resonance: Resonance

Implementation Method 2

a lossy optical resonator consisting of two reflective layers 2, 7 for reflecting light

Methodology Applied
Scientific EffectLight reflection: Reflection

Implementation Method 3

a layer 4 which has been structured photolithographically and which consists of photochemically crosslinkable materials

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentEP2356711B1Organic light-emitting diode having optical resonator in addition to production method
Publication Date: 2020.06.10 UNIVERSITY OF COLOGNE
  • EP2356711B1 patent drawingFigure 1
  • EP2356711B1 patent drawingFigure 2
  • EP2356711B1 patent drawingFigure 3

AI summary

The invention relates to an organic light-emitting diode, known under the abbreviation OLED, and to a method for the production of such an organic light-emitting diode. According to the invention, an OLED or organic light-emitting diode having an emitter layer (5) is produced, said emitter layer emitting white light in particular. The emitter layer (5) is arranged within a lossy, optical resonator. The optical path length between the two reflecting layers of the resonator determines the color of the light emitting from the optical resonator and, consequently, from the light-emitting diode. In order to be able to create a variety of colors, there must be different optical path lengths between the two reflecting surfaces. The correspondingly different distances can be produced in only one work step, in contrast to the prior art, by a photolithographic method. The result is an organic light-emitting diode having a lossy optical resonator, having an emitter layer (5) and a layer (4) that can be photolithographically structured. Said layer (4) is comprised of photochemically curable materials. Organic light-emitting diodes according to the invention can be used in light sources, lighting, sensors or spectrometers.