Organic Light-Emitting Device Composition with Sensitizer Dopant Host

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current organic light-emitting devices face challenges in achieving high efficiency and long lifespan due to issues with exciton recombination and energy transfer, leading to reduced performance and lifespan.

Innovation Solution

A composition comprising a first compound, a second compound, and a third compound is used in the organic light-emitting device, where the first compound acts as a sensitizer, the second compound as a dopant, and the third compound as a host, optimizing energy transfer and exciton management to enhance efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic light-emitting devices are used, then device structure is simple, but efficiency and lifespan are reduced due to exciton recombination and energy transfer issues

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidenergy loss from exciton recombination
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The emission layer is segmented into multiple functional components: host compound, sensitizer compound, and dopant compound. Each component performs a specific function in the energy transfer chain, allowing optimization of each segment independently to improve overall efficiency and reduce energy loss.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The sensitizer compound acts as an intermediary between the host compound and the dopant compound. It receives energy from the host and transfers it to the dopant, facilitating efficient energy transfer and reducing direct exciton recombination losses in the host-dopant system.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Duration of action of stationary object

If conventional emission layers are used, then device complexity is low, but lifespan is reduced due to poor exciton management

Engineering Contradiction:
Improvedevice lifespanVSAvoidcomposition complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The emission layer is divided into distinct functional components (host, sensitizer, dopant) with specific roles in exciton management. This segmentation allows each component to be optimized for its specific function, improving overall device lifespan through better exciton management despite increased compositional complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent specifies particular energy level relationships between compounds (triplet energy levels, singlet energy levels) to optimize exciton management. By controlling these energy parameters, the system achieves improved lifespan through efficient energy transfer pathways while managing the complexity through defined compositional criteria.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If energy transfer is not optimized, then composition is simple, but light-emission characteristics are poor

Engineering Contradiction:
Improvelight emission intensityVSAvoidenergy transfer inefficiency
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The sensitizer compound serves as an intermediary that bridges the host and dopant compounds, enabling efficient energy transfer. This intermediary mechanism optimizes light emission intensity by ensuring effective energy transfer through the system while minimizing energy loss at each transfer step.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes light emission by controlling specific energy level parameters: the triplet energy level of the host, the singlet energy level of the sensitizer, and the energy levels of the dopant. These parameter optimizations enable efficient energy transfer and improved illumination intensity while managing energy transfer efficiency.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves the efficiency and lifespan of organic light-emitting devices by optimizing energy transfer and exciton management, resulting in improved light-emission characteristics and reduced energy loss.

Implementation Method 1

the first compound acts as a sensitizer, the second compound as a dopant, and the third compound as a host, optimizing energy transfer and exciton management to enhance efficiency and lifespan

Methodology Applied
Scientific EffectEnergy transfer: Fluorescence

Implementation Method 2

The holes and the electrons recombine in the emission layer to produce excitons. These excitons transition from an excited state to a ground state to thereby generate light, for example, visible light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20230078199A1Composition and organic light-emitting device including the same
Publication Date: 2023.03.16 SAMSUNG ELECTRONICS CO LTD
  • US20230078199A1 patent drawing
  • US20230078199A1 patent drawing
  • US20230078199A1 patent drawing

AI summary

A composition comprising a first compound, a second compound, and a third compound, wherein the first compound, the second compound, and the third compound are different from each other, the first compound satisfies one of Condition 1 and Condition 2 as described herein, and the second compound includes a compound represented by Formula 1:wherein ring A1 is a condensed cyclic group in which 3 or more cyclic groups are condensed with each other, and the 3 or more cyclic groups are each a C5-C30 carbocyclic group or a C1-C30 heterocyclic group; a1 is an integer from 1 to 5; b1 is an integer from 3 to 10; and L1, R1, and R2 are as described herein.