Organic Light-Emitting Device Compound for Stability and Efficiency

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Solution Overview

Problem

Existing organic light-emitting devices face challenges with electrical stability, charge-transfer capability, and high glass transition temperature to prevent crystallization, which affect their efficiency and longevity.

Innovation Solution

A novel organic compound represented by Formula 1 is introduced, featuring improved electrical characteristics and a high glass transition temperature, suitable for use in organic light-emitting devices as a light-emitting material for various colors, including red, green, blue, and white, with a structure that includes a first and second electrode and an organic layer between them.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing unimolecular materials are used in OLEDs, then the device structure and operation are simple, but the electrical stability is poor and charge-transfer capability is insufficient

Engineering Contradiction:
Improveelectrical stabilityVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite molecular structures combining electron-donating units (carbazole, triphenylamine) with electron-accepting units (pyrene, perylene). This composite approach creates materials with balanced charge transport properties and improved electrical stability while maintaining reasonable structural complexity through systematic molecular design

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If existing organic compounds are used, then the manufacturing process is simple, but the glass transition temperature is insufficient to prevent crystallization

Engineering Contradiction:
Improvecrystallization resistanceVSAvoidsynthesis complexity
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The patent systematically modifies molecular parameters including introducing bulky substituents (tert-butyl groups, adamantyl groups) and extending conjugation systems to elevate glass transition temperatures above 100°C. These parameter changes prevent crystallization during device operation while maintaining compatibility with standard vacuum deposition and solution processing techniques

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If existing materials are used in OLEDs, then the device structure is simple, but the emission capability and luminance efficiency are insufficient

Engineering Contradiction:
Improveluminance efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent applies local quality enhancement by incorporating specific light-emitting moieties (pyrene for blue emission, perylene for red emission) into the molecular structure. These localized functional units provide high quantum efficiency and characteristic emission wavelengths while the overall molecular framework maintains structural integrity and charge transport capability

Inventive Principle:
Principle #3Local quality

4Reliability

If existing organic compounds are used, then the charge transport capability is moderate, but the electrical characteristics and durability are insufficient

Engineering Contradiction:
ImprovedurabilityVSAvoidcharge transport capability
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent designs amphoteric organic compounds that simultaneously exhibit both hole-transporting and electron-transporting capabilities. This multi-functionality is achieved by incorporating both electron-donating (carbazole, triphenylamine) and electron-accepting (pyrene, perylene) units in the same molecular structure, enabling the material to serve multiple functions and improve overall device durability

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The novel organic compound enhances the durability and efficiency of organic light-emitting devices by providing high luminance, low driving voltage, and long lifetime, while preventing crystallization and maintaining heat resistance.

Implementation Method 1

When a voltage is applied between the anode and the cathode, holes injected from the anode move to the EML via the HTL, and electrons injected from the cathode move to the EML via the ETL. The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9196838B2Organic compound and organic light-emitting device comprising the same
Publication Date: 2015.11.24 SAMSUNG DISPLAY CO LTD
  • US9196838B2 patent drawing
  • US9196838B2 patent drawing
  • US9196838B2 patent drawing

AI summary

An organic compound represented by Formula 1 below and an organic light-emitting device including the organic compound;Wherein Ar1, Ar2, Ar3, Ar4, a, b, and c are defined as in the specification.