Organic Light Emitting Element Energy Level Management

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Solution Overview

Problem

Current organic light emitting devices face challenges in achieving high efficiency and long lifetime due to limitations in material selection and energy level management between layers, leading to suboptimal driving voltage and stability.

Innovation Solution

Incorporating a compound with a specific chemical structure, such as Chemical Formula 1, in the electron control layer and Chemical Formula 3 in the light emitting layer, which features a deep HOMO energy level and tailored molecular structure to enhance electron mobility and block holes effectively, thereby optimizing energy levels and layer interactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic materials are used in the electron control layer and light emitting layer, then the device structure is simple, but the light emission efficiency is low and device lifetime is short

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by carefully selecting organic compounds with specific HOMO energy levels for different layers. The electron control layer uses compounds with HOMO levels of 6.0 eV or higher, while the light emitting layer uses compounds with HOMO levels of 5.5-6.5 eV. This energy level parameter optimization enables efficient electron injection and transport, significantly improving light emission efficiency and device lifetime without overly complicating the material structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining specific organic compounds in a multi-layer structure. The electron control layer incorporates compounds like BCP or TPBi, while the light emitting layer uses host-guest systems with specific dopants. This composite approach creates synergistic effects that enhance electron mobility and recombination efficiency, resolving the contradiction between efficiency improvement and structural simplicity.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If the HOMO energy level is not optimized between layers, then the material selection is easy, but the driving voltage is high and energy efficiency is low

Engineering Contradiction:
Improveenergy efficiencyVSAvoidenergy level management complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent systematically optimizes the HOMO energy level parameter across different layers to achieve efficient energy transfer. By establishing a gradient where the electron control layer has HOMO ≥ 6.0 eV and the light emitting layer has HOMO of 5.5-6.5 eV, the patent enables smooth electron injection and reduces energy barriers, thereby lowering driving voltage and improving overall energy efficiency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The electron control layer acts as an intermediary between the cathode and the light emitting layer, mediating electron injection and transport. This intermediate layer with specifically tuned HOMO energy level (≥6.0 eV) facilitates efficient electron transfer from the cathode to the light emitting layer, reducing energy loss and improving energy efficiency without requiring complex energy level management in the other layers.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If conventional electron control materials are used, then the device manufacturing is simple, but electron mobility is insufficient and device stability is poor

Engineering Contradiction:
Improvedevice stabilityVSAvoidmaterial selection complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent improves device stability by selecting electron control layer compounds with HOMO energy levels of 6.0 eV or higher, such as BCP or TPBi. This parameter-based selection ensures adequate electron blocking capability and thermal stability, significantly enhancing device reliability and operational stability while maintaining relatively simple manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in improved light emission efficiency, reduced driving voltage, and extended device lifetime by effectively managing energy levels and electron mobility within the organic light emitting device.

Implementation Method 1

the compound of Chemical Formula 1 has a HOMO energy level of 6.0 eV or more

Methodology Applied
Scientific EffectHOMO energy level:

Implementation Method 2

tailored molecular structure to enhance electron mobility

Methodology Applied
Scientific EffectElectron mobility:

Implementation Method 3

when the injected holes and electrons meet, excitons are formed, and light emits when these excitons fall back to the ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11462695B2Organic light emitting element
Publication Date: 2022.10.04 LG CHEM LTD
  • US11462695B2 patent drawing
  • US11462695B2 patent drawing
  • US11462695B2 patent drawing

AI summary

Provided is an organic light emitting device including an anode; a cathode; and a light emitting layer provided between the anode and cathode, wherein an electron control layer provided between the light emitting layer and the cathode and including a compound of Chemical Formula 1:is included, and the light emitting layer includes a compound of Chemical Formula 3: