Olefinic Ester Cleaning Agents via Metathesis

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Solution Overview

Problem

There is a need for solvent compounds that are renewably sourced, exhibit high solvency, and have a desirable health and safety profile, particularly in terms of toxicity and volatile organic compounds (VOCs), as traditional high VOC solvents are environmentally harmful and pose health risks.

Innovation Solution

The development of olefinic ester compounds, specifically esters of C10-18 carboxylic acids with one or more carbon-carbon double bonds, which are used in cleaning compositions for surfaces, textiles, and food-related materials, derived from natural oils through catalytic olefin metathesis, offering improved solvency and reduced toxicity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional high VOC solvents (aromatics, ketones, halogenated organics) are used, then high solvency is achieved, but environmental harm and health risks increase

Engineering Contradiction:
Improveenvironmental harm and health risksVSAvoidsolvency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the chemical parameters of solvent molecules by introducing carbon-carbon double bonds into ester structures derived from renewable feedstocks. This structural modification enables the solvents to achieve high solvency comparable to traditional solvents while simultaneously reducing VOC content and improving environmental compatibility, thus resolving the contradiction between solvency and environmental harm.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite solvent systems by combining olefinic ester compounds with specific physical and chemical properties. These composite materials integrate the benefits of renewable sourcing, low VOC content, and high solvency into a unified solvent system that outperforms traditional single-component solvents in both effectiveness and environmental safety.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If renewable solvents (fatty acid alkyl esters, terpene oils) are used, then environmental friendliness is improved, but solvency performance deteriorates

Engineering Contradiction:
Improveenvironmental friendlinessVSAvoidsolvency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent modifies the molecular parameters of renewable ester solvents by incorporating carbon-carbon double bonds through olefin metathesis reactions. This structural change enhances the solvent properties of renewable feedstocks, enabling them to achieve solvency levels comparable to or exceeding traditional solvents while maintaining their environmental advantages, thus resolving the contradiction between environmental friendliness and solvency.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If solvents with low toxicity are developed, then health safety is improved, but solvency may be compromised

Engineering Contradiction:
ImprovetoxicityVSAvoidsolvency
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the molecular structure of esters by introducing carbon-carbon double bonds, which simultaneously improves biodegradability and reduces toxicity while maintaining or enhancing solvency. The resulting olefinic ester compounds achieve a balanced profile where low toxicity does not come at the expense of cleaning effectiveness.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The olefinic ester compounds provide effective cleaning performance while minimizing environmental impact and health risks, offering a sustainable alternative to traditional solvents with enhanced solvency and lower VOC levels.

Implementation Method 1

olefinic ester compounds are derived from a natural oil or a natural oil derivative, for example, by catalytic olefin metathesis

Methodology Applied
Scientific EffectOlefin metathesis: Chemical Bonding

Data Source

PatentUS10858573B2Olefinic ester compositions and their use as cleaning agents
Publication Date: 2020.12.08 WILMAR TRADING PTE LTD
  • US10858573B2 patent drawing
  • US10858573B2 patent drawing

AI summary

Compositions including olefinic ester compounds are generally disclosed. In some embodiments, such compositions are cleaning compositions, and can be used to clean various surfaces (e.g., hard surfaces, etc.) and/or materials (e.g., textiles, fibers, etc.). In some embodiments, the olefinic ester compounds are derived from a natural oil or a natural oil derivative, for example, by catalytic olefin metathesis.