Oligomer Composition for Low Dielectric PCB Substrates

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Solution Overview

Problem

Conventional materials used in printed circuit boards have high dielectric constants and dissipation factors, which hinder the achievement of high-density, high-frequency transmission and signal integrity, necessitating the development of novel materials with lower dielectric constants and dissipation factors.

Innovation Solution

An oligomer with a controlled number average molecular weight of 1,000 to 10,000, derived from specific reactants through addition polymerization, is developed, which exhibits high thermal stability, solubility, and compatibility with conventional resins, forming a composition with a crosslinking agent that results in a cured product with low dielectric constant and dissipation factor, suitable for high-frequency substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional materials are used for printed circuit boards, then manufacturing is easier and cost is lower, but dielectric constant and dissipation factor are high which deteriorates transmission signal integrity

Engineering Contradiction:
Improvetransmission signal integrityVSAvoidmaterial processing
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the molecular weight parameter of the oligomer to a specific range (1,000 to 10,000) to achieve low dielectric constant and dissipation factor. This parameter optimization resolves the contradiction by enabling high-frequency signal transmission while maintaining manufacturability through controlled polymerization reactions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining oligomer with specific reactants (Formula I-IV) and crosslinking agents (Formula V-VII). This composite approach achieves both low dielectric properties for signal integrity and compatible manufacturing characteristics through the synergistic combination of multiple components.

Inventive Principle:
Principle #40Composite materials

2Strength

If oligomer molecular weight is increased to improve mechanical strength, then material strength increases, but processability and solubility deteriorate

Engineering Contradiction:
Improvemechanical strengthVSAvoidprocessability
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent optimizes the molecular weight parameter within the specific range of 1,000 to 10,000, which is high enough to provide mechanical strength but low enough to maintain good solubility and processability. This parameter window resolves the contradiction between strength and ease of manufacture.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups (Formula I-IV) at local positions within the oligomer structure, which provide crosslinking capability for strength while the overall low molecular weight maintains processability. The local functional groups enable strength without requiring high overall molecular weight.

Inventive Principle:
Principle #3Local quality

3Strength

If crosslinking density is increased to improve mechanical properties, then strength and thermal stability increase, but dielectric constant and dissipation factor increase

Engineering Contradiction:
Improvemechanical strengthVSAvoiddielectric constant
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the crosslinking density by selecting specific crosslinking agents (Formula V-VII) and controlling their ratio, achieving sufficient mechanical strength while maintaining low dielectric constant and dissipation factor. The parameter optimization prevents excessive crosslinking that would increase dielectric properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent ensures homogeneous distribution of crosslinking agents throughout the oligomer matrix, creating uniform crosslinking density. This homogeneity allows for optimal balance between mechanical strength and dielectric properties, avoiding localized regions of high crosslinking that would increase dielectric constant.

Inventive Principle:
Principle #33Homogeneity

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The oligomer-based composition enhances mechanical strength and processability, reducing phase separation and achieving a low dielectric constant and dissipation factor, thereby improving insertion loss and suitability for high-frequency applications.

Implementation Method 1

The oligomer can be a reaction product of a reactant (a) and a reactant (b)... the reactant (c) is a compound having a structure represented by Formula (V), a compound having a structure represented by Formula (VI)... the reactant (d) is a compound having a structure represented by Formula (VII)

Methodology Applied
Scientific EffectAddition polymerization:

Data Source

PatentUS10179833B2Oligomer, composition and composite material employing the same
Publication Date: 2019.01.15 IND TECH RES INST
  • US10179833B2 patent drawing
  • US10179833B2 patent drawing
  • US10179833B2 patent drawing

AI summary

An oligomer, composition, and composite material employing the same are provided. The oligomer can be a reaction product of a reactant (a) and a reactant (b). The reactant (a) is a reaction product of a reactant (c) and a reactant (d). The reactant (b) can beor a combination thereof, wherein a is 0 or 1, and R1 is independently hydrogen orand wherein b is 0-6; c is 0 or 1; and, d is 0-6. The reactant (c) iswherein R2 is C5-10 alkyl group. The reactant (d) iswherein e is 0-10.