Oligomerization Reactor Mode Switching via Olefin HCl Ratio

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Solution Overview

Problem

Current processes for producing distillate and lubricant products lack the ability to efficiently switch between producing distillates and lubricants, as existing technologies are limited in their capacity to adjust product boiling ranges and catalyst configurations to meet market demands.

Innovation Solution

A process unit comprising an oligomerization reactor and a control system that allows for operation in both distillate and lubricant modes by adjusting the molar ratio of olefin to HCl, enabling greater than 50 wt % of the C5+ product stream to boil above or below 700° F, and switching between modes to produce either distillate or lubricant products based on market demands.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If existing technologies are used to produce distillate or lubricant products, then production of a single product type is achieved, but the ability to switch between product types efficiently is lost

Engineering Contradiction:
Improveability to switch between distillate and lubricant productionVSAvoidproduction efficiency
Core Design Contradiction:
Adaptability or versatilityVSProductivity

Solution Approach 1:

The process unit employs dynamic control of reaction parameters including temperature, pressure, and olefin to HCl molar ratio to switch between distillate and lubricant production modes. The system transitions from static single-product design to dynamic multi-product capability by adjusting operating conditions in real-time based on market demands.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention utilizes parameter changes in the oligomerization reaction conditions, specifically varying the olefin to HCl molar ratio and reaction temperature, to control the boiling range distribution of the C5+ product stream. By changing these parameters, the system can produce either distillate (greater than 50 wt% boiling at 700°F or below) or lubricant (greater than 50 wt% boiling above 700°F) products.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If product boiling range is adjusted to meet market demands, then product versatility is improved, but process complexity increases

Engineering Contradiction:
Improveproduct boiling range adjustment capabilityVSAvoidprocess unit complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The process unit achieves multi-functionality by using a single oligomerization reactor configuration to produce both distillate and lubricant products. The same reactor, catalyst system, and basic process flow can be adjusted to produce different product types, eliminating the need for separate production lines for each product category.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

Instead of adding complex equipment to change product properties, the invention relies on adjusting reaction parameters (temperature, pressure, olefin to HCl ratio) to control the boiling range distribution. This parameter-based control achieves product versatility without proportionally increasing device complexity.

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If catalyst configuration is changed to produce different products, then product range is expanded, but operational complexity and switching time increase

Engineering Contradiction:
Improveproduct range through catalyst adjustmentVSAvoidswitching time between production modes
Core Design Contradiction:
Adaptability or versatilityVSLoss of time

Solution Approach 1:

The system implements dynamic operation where the same catalyst configuration can produce different product ranges by adjusting operating parameters. This eliminates the need for physical catalyst changes or reconfigurations when switching between distillate and lubricant production, significantly reducing switching time and operational complexity.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables flexible production of either distillate or lubricant products by adjusting the olefin to HCl molar ratio, allowing for efficient switching between modes to meet market demands, reducing production complexity and equipment needs while maintaining catalyst activity.

Implementation Method 1

an oligomerization reactor and a control system that enables the oligomerization reactor to be operated in a distillate mode

Methodology Applied
Scientific EffectOligomerization: Chemical Bonding

Data Source

PatentUS8871154B2Oligomerization reactor and control system
Publication Date: 2014.10.28 CHEVRON USA INC
  • US8871154B2 patent drawing
  • US8871154B2 patent drawing
  • US8871154B2 patent drawing

AI summary

A process unit, having:a) an oligomerization reactor; andb) a control system that enables the reactor to be operated in a distillate mode and in a lubricant mode; and wherein the reactor can switch between modes.