Olive Stone Polyethylene Composite Adsorbent Flakes

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Solution Overview

Problem

Conventional methods for removing organic dyes and other pollutants from wastewater are inefficient due to high water solubility and require filtration systems, making them costly and environmentally unfriendly.

Innovation Solution

A method for preparing porous activated carbon composite flakes using olive stones and polyethylene waste, involving alkali-activation, pyrolysis, acid-activation, and annealing, which creates adsorbent flakes with a high surface area for effective pollutant removal without the need for filtration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional activated carbon powder is used for dye removal, then adsorption capacity is achieved, but filtration membrane and technique are required for separation

Engineering Contradiction:
Improveadsorption capacityVSAvoidfiltration system requirement
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent combines activated carbon particles with a thermoplastic polymer matrix to create a composite adsorbent. This composite structure integrates the high adsorption capacity of activated carbon with the mechanical strength and filterability of the polymer, eliminating the need for separate filtration membranes while maintaining effective dye removal capability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The thermoplastic polymer forms a matrix that encapsulates the activated carbon particles, creating a self-contained adsorbent structure. This polymer matrix acts as an inherent filtering medium that allows easy separation from wastewater through simple filtration or settling, replacing complex filtration membrane systems

Inventive Principle:
Principle #30Flexible shells and thin films

2Reliability

If activated carbon is used for pollutant removal, then adsorption effectiveness is improved, but cost and environmental impact increase due to filtration requirements

Engineering Contradiction:
Improvepollutant removal effectivenessVSAvoidcost and environmental friendliness
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The composite adsorbent is designed to be self-contained, with the polymer matrix providing both structural integrity and filtration capability. The material can be directly applied to wastewater, performs adsorption, and can be easily removed without requiring complex filtration infrastructure, reducing both manufacturing cost and environmental impact

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The composite adsorbent can be easily separated from treated water due to its particulate nature and polymer matrix structure, allowing for simple recovery and potential regeneration or disposal without expensive filtration equipment

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces adsorbent flakes with a large surface area and high adsorption capacity, enabling efficient removal of pollutants like organic dyes from wastewater without requiring filtration systems, and can be reused after desorption.

Implementation Method 1

alkali-activating the dried olive stone pieces to obtain alkali-activated olive stone pieces

Methodology Applied
Scientific EffectAlkali activation:

Implementation Method 2

pyrolyzing the alkali-activated olive stone pieces to obtain alkali-activated olive stone char

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 3

acid-activating the alkali-activated olive stone char to obtain acid-activated olive stone char

Methodology Applied
Scientific EffectAcid activation:

Implementation Method 4

dissolving at least one polymer in an organic solvent to obtain a polymer solution; dispersing the acid-activated olive stone char in the polymer solution to obtain a mixture

Methodology Applied
Scientific EffectPolymerization:

Implementation Method 5

annealing the composite to provide the adsorbent

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 6

The adsorbent flakes can be used for enhanced removal of pollutants from wastewater

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS11896950B1Activated carbon composite flakes using olive stone-polyethylene waste
Publication Date: 2024.02.13 KING FAISAL UNIV
  • US11896950B1 patent drawing

AI summary

A method of preparing an adsorbent can include pyrolyzing olive stone to provide an olive stone char, activating the olive stone char, dissolving a polymer in an organic solvent to obtain a solution, dispersing the activated olive stone char in the solution to provide a mixture, extracting the solvent from the mixture to provide a composite, and annealing the composite to provide the adsorbent. The adsorbent can be porous.