Omnidirectional Structural Color via Amorphous TiO2 Multilayer

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Solution Overview

Problem

Forming multilayer thin film structures with omnidirectional structural color is challenging due to the complexity and cost of deposition techniques, which often result in variations that affect the color produced, and achieving precise layer thickness control is difficult, especially when depositing on reflective core layers using conventional methods.

Innovation Solution

A multilayer thin film structure comprising a reflective core layer, an amorphous-phase TiO2 dielectric layer, a metallic absorbing layer, and a dielectric outer layer, deposited using a combination of CVD, ALD, and wet chemical methods, which reduces costs and enhances efficiency while maintaining precise control over layer thicknesses, minimizing color shift when viewed from different angles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional deposition techniques are used to form multilayer thin film structures, then the manufacturing process is simpler and less costly, but the manufacturing precision and control over layer thickness are insufficient, resulting in color variations

Engineering Contradiction:
Improvelayer thickness controlVSAvoiddeposition technique complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by transitioning from conventional deposition techniques to atomic layer deposition (ALD), which provides precise control over layer thickness through controlled deposition parameters. ALD allows for atomic-level precision in controlling the thickness of each layer, ensuring consistent optical properties and minimizing color variations while maintaining a manageable manufacturing process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces conventional mechanical deposition methods with a chemically-controlled ALD process. This substitution enables precise thickness control through chemical reactions that occur in a controlled sequence, allowing for better manufacturing precision without excessive complexity in the deposition system

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional deposition techniques are used, then the manufacturing process is faster and less costly, but the reliability of achieving consistent omnidirectional color is reduced

Engineering Contradiction:
Improvecolor consistencyVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent implements feedback control through the self-limiting nature of ALD processes, where each deposition cycle is precisely controlled and can be monitored. This feedback mechanism ensures that each layer is deposited with consistent thickness and properties, achieving reliable omnidirectional color consistency while maintaining manufacturing efficiency through automated, repeatable processes

Inventive Principle:
Principle #23Feedback

3Manufacturing precision

If precise layer thickness control is achieved through advanced deposition techniques, then the color consistency is improved, but the manufacturing cost and time increase

Engineering Contradiction:
Improvecolor accuracyVSAvoiddeposition time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent applies preliminary action by carefully designing and optimizing the deposition parameters and layer sequences before manufacturing. The multilayer structure is pre-planned with specific thicknesses and material compositions that achieve the desired omnidirectional color effect, allowing for efficient deposition without excessive time or cost while maintaining high color accuracy

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The structure achieves a minimal color shift of less than 30° in Lab color space when viewed from angles between 0° and 45°, reflecting a single narrow band of visible light omnidirectionally, thereby providing a cost-effective and efficient solution for achieving high-chroma structural colors.

Implementation Method 1

the multilayer thin film reflects a single narrow band of visible light when exposed to broadband electromagnetic radiation

Methodology Applied
Scientific EffectOptical interference: Interference

Implementation Method 2

a metallic absorbing layer extending across the amorphous-phase TiO2 dielectric layer

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Implementation Method 3

an amorphous-phase TiO2 dielectric layer extending across the reflective core layer

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS20240053521A1Omnidirectional structural color microstructures comprising titanium dioxide
Publication Date: 2024.02.15 TOYOTA MOTOR ENG & MFG NORTH AMERICA INC
  • US20240053521A1 patent drawing
  • US20240053521A1 patent drawing
  • US20240053521A1 patent drawing

AI summary

A multilayer thin film that reflects an omnidirectional structural color having a reflective core layer; an amorphous-phase TiO2 dielectric layer extending across the reflective core layer; a metallic absorbing layer extending across the dielectric layer; and a dielectric outer layer extending across the metallic absorbing layer. The multilayer thin film reflects a single narrow band of visible light when exposed to broadband electromagnetic radiation, and a color shift of the single narrow band of visible light is less than 30° measured in Lab color space when the multilayer thin film is exposed to broadband electromagnetic radiation and viewed from angles between 0° and 45° relative to a direction normal to an outer surface of the multilayer thin film.