On-array ligation assembly for DNA construct synthesis

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Solution Overview

Problem

Current high-throughput methods for DNA construct assembly are labor-intensive and costly due to the high reagent requirements for joining shorter oligonucleotides into longer constructs, despite advancements in polymerase or ligase enzyme-based methods.

Innovation Solution

A method involving hybridization of double-stranded oligonucleotides to a substrate with surface-tethered oligonucleotides, followed by ligation of surface-distal ends to produce a ligation product tethered to the support at both ends, allowing for efficient assembly and subsequent cleavage to extend the construct.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Extent of automation

If automated robotic systems with micro-titer plates are used for DNA assembly, then labor costs are reduced, but reagent costs and complexity increase due to multiple reactions required

Engineering Contradiction:
Improveautomated robotic systemVSAvoidreagent cost
Core Design Contradiction:
Extent of automationVSQuantity of substance

Solution Approach 1:

The DNA assembly process is segmented into two distinct phases: (1) hybridization of double-stranded oligonucleotides to surface-tethered oligonucleotides on a solid support, and (2) ligation of the surface-distal ends. This segmentation allows the oligonucleotides to be immobilized during assembly, enabling washing away of excess reagents and reducing the quantity of reagents needed compared to traditional solution-based methods that require multiple sequential reactions in micro-titer plates.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from traditional two-dimensional micro-titer plate-based assembly to a three-dimensional solid support system where oligonucleotides are tethered to a surface. This dimensional change allows for efficient immobilization and reduces reagent consumption by confining the reaction to the surface-bound molecules rather than requiring excess reagents in solution phase.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Adaptability or versatility

If traditional oligonucleotide assembly methods are used, then flexibility in method selection exists, but labor intensity and reagent consumption increase

Engineering Contradiction:
Improvemethod selection flexibilityVSAvoidlabor intensity
Core Design Contradiction:
Adaptability or versatilityVSLoss of time

Solution Approach 1:

The solid support performs a self-service function by automatically immobilizing the hybridized double-stranded oligonucleotides during the hybridization step. This self-immobilization eliminates the need for manual transfer operations and reduces labor intensity. The surface-tethered oligonucleotides serve as both the substrate and the anchoring mechanism, streamlining the process while maintaining versatility in oligonucleotide sequence selection.

Inventive Principle:
Principle #25Self-service

3Reliability

If multiple sequential reactions are performed in micro-titer plates, then complete assembly can be achieved, but process complexity and reagent volume increase

Engineering Contradiction:
Improveassembly completionVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges the hybridization and ligation steps into a streamlined two-step process on a solid support. The surface-tethered oligonucleotides remain stationary during both steps, allowing excess reagents to be washed away between steps without requiring complex liquid handling operations. This merging of steps on a fixed support reduces process complexity compared to performing multiple sequential reactions in micro-titer plates while ensuring complete assembly through thorough washing and controlled reaction conditions.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces reagent costs and labor by enabling efficient assembly of DNA constructs on a support, facilitating the production of longer DNA sequences while minimizing the need for extensive reagent usage and optimizing the assembly process.

Implementation Method 1

hybridizing a first double-stranded oligonucleotides and a second double-stranded oligonucleotide to a substrate comprising surface-tethered oligonucleotides

Methodology Applied
Scientific EffectHybridization: Chemical Bonding

Implementation Method 2

ligating the surface-distal ends of the first and second double-stranded oligonucleotides together, thereby producing a first ligation product

Methodology Applied
Scientific EffectLigation: Chemical Bonding

Data Source

PatentEP3309252B1On-array ligation assembly
Publication Date: 2020.07.15 AGILENT TECHNOLOGIES INC
  • EP3309252B1 patent drawingFigure 1
  • EP3309252B1 patent drawingFigure 2~3
  • EP3309252B1 patent drawingFigure 4~5

AI summary

Provided herein, among other things, is a method for producing a ligation product on a support. In some embodiments, the method may comprise hybridizing a first double-stranded oligonucleotides and a second double-stranded oligonucleotide to a substrate comprising surface-tethered oligonucleotides and ligating the distal ends of the first and second double-stranded oligonucleotides together, thereby producing a first ligation product that is tethered to the support at both ends.