On-axis SiC Etching for Precise MEMS Structures

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Solution Overview

Problem

Existing methods for etching silicon carbide (SiC) materials, particularly off-axis SiC, suffer from poor etch symmetry, straightness, sidewall smoothness, and high sidewall wander, which hinder the formation of precise microelectromechanical structures.

Innovation Solution

The method involves etching hexagonal, single-crystal silicon carbide materials on-axis or near on-axis with respect to the c-axis, using deep reactive-ion etching (RIE) and applying an etch mask, which improves etch symmetry, straightness, and sidewall smoothness, and reduces sidewall wander, enabling the creation of high-aspect-ratio features.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If off-axis SiC material is etched using existing methods, then etching can be performed, but etch symmetry is poor and sidewall wander is high

Engineering Contradiction:
Improveetch symmetryVSAvoidsidewall wander
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The patent changes the crystallographic orientation parameter of the SiC material from off-axis to on-axis (changing the angle parameter from 4° off-axis to within 0.5° of on-axis). This parameter change fundamentally improves etch symmetry and reduces sidewall wander during RIE processing, as the on-axis orientation provides more uniform etching characteristics across the crystal structure.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If off-axis SiC material is etched, then etching can proceed, but sidewall smoothness is poor

Engineering Contradiction:
Improvesidewall smoothnessVSAvoidetching process
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent modifies the crystal orientation parameter from off-axis to on-axis SiC, which fundamentally improves sidewall smoothness during etching. The on-axis orientation (within 0.5° of on-axis) provides more uniform atomic planes that etch more evenly, producing smoother sidewalls without requiring additional process complexity.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If off-axis SiC material is etched, then etching can be performed, but etch straightness is poor

Engineering Contradiction:
Improveetch straightnessVSAvoidetching process
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent changes the crystallographic orientation parameter from off-axis to on-axis SiC material. This parameter change ensures that the etching process follows straight, predictable paths along the crystal planes, significantly improving etch straightness. The on-axis orientation provides symmetric crystal planes that guide the etch front uniformly, eliminating the wandering and curvature issues seen with off-axis materials.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in improved etch symmetry, straightness, and smoothness, and reduced sidewall wander, allowing for the formation of precise microelectromechanical structures such as beams, membranes, and field effect transistor devices with high aspect ratios.

Implementation Method 1

Plasma-etched hexagonal single-crystal SiC materials

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 2

conducting deep reactive-ion etching (RIE) of the SiC material

Methodology Applied
Scientific EffectReactive-ion etching:

Data Source

PatentUS10343900B2Material structure and method for deep silicon carbide etching
Publication Date: 2019.07.09 THE GOVERNMENT OF THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY DEPARTMENT OF HEALTH & HUMAN SERVICES
  • US10343900B2 patent drawing
  • US10343900B2 patent drawing
  • US10343900B2 patent drawing

AI summary

Material structures and methods for etching hexagonal, single-crystal silicon carbide (SiC) materials are provided, which include selection of on-axis or near on-axis hexagonal single-crystal SiC material as the material to be etched. The methods include etching of SiC bulk substrate material, etching of SiC material layers bonded to a silicon oxide layer, etching of suspended SiC material layers, and etching of a SiC material layer anodically bonded to a glass layer. Plasma-etched hexagonal single-crystal SiC materials of the invention may be used to form structures that include, but are not limited to, microelectromechanical beams, microelectromechanical membranes, microelectromechanical cantilevers, microelectromechanical bridges, and microelectromechanical field effect transistor devices. The material structures and methods of the invention beneficially provide improved etch symmetry, improved etch straightness, improved sidewall straightness, improved sidewall smoothness, and reduced sidewall wander compared to etched four degree off-axis SiC materials.