Optical 3D Modeling Composition with UV-Absorbing Inorganic Particles

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Solution Overview

Problem

Existing optical three-dimensional modeling techniques face challenges in achieving desirable shape accuracy and transparency, especially when inorganic particles are added to enhance mechanical characteristics, such as in dental materials, where the properties of these particles lead to poor shape accuracy due to light scattering.

Innovation Solution

A composition comprising a polymerizable monomer, ultraviolet-absorbing inorganic particles, and a photopolymerization initiator, specifically using (meth)acrylate and (meth)acrylamide monomers, zinc oxide, and surface-treated inorganic particles, which improves shape accuracy and mechanical characteristics while maintaining transparency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If inorganic particles are added to the light-curable resin composition to improve mechanical characteristics, then strength is improved, but shape accuracy deteriorates due to light scattering

Engineering Contradiction:
Improvemechanical strengthVSAvoidshape accuracy
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent changes the particle size parameter of inorganic particles to 1 µm or smaller, which fundamentally alters the light interaction characteristics. At this size scale, the particles no longer scatter light significantly, thereby maintaining shape accuracy while preserving the mechanical strength enhancement benefit

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite resin composition containing polymerizable monomers, photopolymerization initiators, and specifically sized inorganic particles (1 µm or smaller). This composite structure enables simultaneous achievement of improved mechanical characteristics and maintained shape accuracy through the synergistic combination of materials with optimized properties

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the resin composition is optimized for shape accuracy without inorganic particles, then shape accuracy is improved, but mechanical characteristics deteriorate

Engineering Contradiction:
Improveshape accuracyVSAvoidmechanical characteristics
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent develops a composite material system that combines organic resin components with specifically sized inorganic particles (1 µm or smaller). This composite approach allows the material to simultaneously achieve the transparency and shape accuracy of organic resins while gaining the mechanical strength enhancement from inorganic particles, eliminating the need to choose between the two properties

Inventive Principle:
Principle #40Composite materials

3Strength

If larger inorganic particles are used to enhance strength, then mechanical characteristics are improved, but transparency and shape accuracy worsen due to increased light scattering

Engineering Contradiction:
Improvemechanical characteristicsVSAvoidtransparency
Core Design Contradiction:
StrengthVSIllumination intensity

Solution Approach 1:

The patent fundamentally changes the particle size parameter from conventional larger sizes to 1 µm or smaller. This parameter change transforms the optical properties of the inorganic particles, reducing light scattering effects and maintaining transparency while still providing mechanical reinforcement. The same parameter change simultaneously improves shape accuracy by reducing light diffusion during curing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves desirable shape accuracy, transparency, and mechanical characteristics, making it suitable for dental applications, with enhanced curability and strength, suitable for producing complex dental prosthetic appliances like crowns and bridges.

Implementation Method 1

a photopolymerization initiator (c)

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Implementation Method 2

ultraviolet-absorbing inorganic particle (b)

Methodology Applied
Scientific EffectUltraviolet absorption: Absorption (EM radiation)

Data Source

PatentEP3530676B1Composition for optical three-dimensional modeling
Publication Date: 2024.08.14 KURARAY NORITAKE DENTAL
  • EP3530676B1 patent drawing
  • EP3530676B1 patent drawing
  • EP3530676B1 patent drawing

AI summary

The present invention provides a composition for optical three-dimensional modeling that offers desirable shape accuracy in optical three-dimensional modeling, and that provides desirable transparency and mechanical characteristics upon being cured. The present invention relates to a composition for optical three-dimensional modeling comprising a polymerizable monomer (a), an ultraviolet-absorbing inorganic particle (b), and a photopolymerization initiator (c).