Optical Adhesive Composition for Display Panels

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Solution Overview

Problem

Existing optical adhesives face challenges in achieving optimal adhesion, minimal curing contraction, and sufficient elongation while avoiding bubble formation between ITO films and glass window layers, which affects the reliability and visibility of display panels.

Innovation Solution

An optical adhesive composition incorporating a urethane (meth)acrylate resin with hydroxyl and vinyl groups, specifically formulated with a curing contraction ratio of 0-3% and adhesion of 30-80 kgf, including a photocurable monomer, photoinitiator, UV absorber, and antioxidant, to ensure stable bonding and minimal stress on substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional optical adhesives are used, then adhesion is achieved, but curing contraction is excessive causing stress on substrates

Engineering Contradiction:
ImproveadhesionVSAvoidcuring contraction stress
Core Design Contradiction:
StrengthVSStress or pressure

Solution Approach 1:

The patent modifies the chemical composition parameters of the adhesive by incorporating specific ratios of urethane polymer (1-10 parts), polyol (5-20 parts), and (meth)acrylic monomer (1-10 parts) to control the curing contraction ratio within 0-5% and maintain adhesion strength of 30-80 kgf

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite adhesive system combining urethane polymer, polyol, and (meth)acrylic monomer in specific proportions to achieve both low curing contraction and high adhesion, preventing substrate stress while maintaining bonding strength

Inventive Principle:
Principle #40Composite materials

2Strength

If adhesive formulation is optimized for adhesion, then bonding strength improves, but elongation becomes insufficient

Engineering Contradiction:
ImproveadhesionVSAvoidelongation
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent adjusts the molecular weight and compositional parameters of the adhesive components, specifically using polyol with molecular weight 500-5000 and controlling the equivalence ratio between polyol and isocyanate (1.05-1.2:1) to simultaneously achieve high adhesion and sufficient elongation (200-800%)

Inventive Principle:
Principle #35Parameter changes

3Stress or pressure

If curing contraction is minimized, then substrate stress is reduced, but adhesion may be compromised

Engineering Contradiction:
Improvecuring contraction stressVSAvoidadhesion
Core Design Contradiction:
Stress or pressureVSStrength

Solution Approach 1:

The patent develops a composite adhesive formulation where urethane polymer (1-10 parts) provides adhesion, polyol (5-20 parts) provides flexibility and elongation, and (meth)acrylic monomer (1-10 parts) controls curing contraction, achieving a balance of 0-5% contraction with 30-80 kgf adhesion

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive composition provides improved adhesion, reduced curing contraction, and enhanced elongation, preventing bubble formation and stress on substrates, thereby enhancing the reliability and outdoor visibility of display panels.

Implementation Method 1

a copolymer of a urethane polymer having at least one hydroxyl group and a (meth)acrylic monomer having an isocyanate and a vinyl group

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 2

The optical adhesive composition may further include a photocurable monomer, a photoinitiator, a UV absorber, and an antioxidant

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS8834670B2Optical adhesive composition and display panel including the same
Publication Date: 2014.09.16 CHEIL INDUSTRIES INC

AI summary

An optical adhesive composition includes a urethane (meth)acrylate resin having at least one hydroxyl group and at least one vinyl group, the urethane (meth)acrylate resin having a curing contraction ratio expressed by Equation 1 of about 0 to about 3%; and an adhesion of about 30 to about 80 kgf:Curing contraction ratio (%)=(A−B)/A×100,  [Equation 1]where A is a specific gravity of the optical adhesive composition before curing, and B is a specific gravity of the solid optical adhesive composition after curing.