Optical Ceramics With 3D Compositional Gradients

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Solution Overview

Problem

Current methods for manufacturing optical ceramics lack the ability to control three-dimensional compositional profiles, leading to non-uniform temperature distribution, beam distortion, and thermal stress fracture, as they cannot achieve smoothly varying compositional gradients in all spatial dimensions.

Innovation Solution

A method involving the deposition and binding of thin layers of optical material powders with varying dopant levels based on three-dimensional design data, using micro-deposition techniques such as electrostatic or electro-photographic deposition, to create optical ceramics with tailored compositional profiles, allowing for uniform dopant distribution and reduced porosity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional manufacturing methods (isopressing, sintering, diffusion bonding) are used to make optical ceramics, then production is achieved with existing technology, but the ability to control three-dimensional compositional profiles and achieve smoothly varying dopant gradients is limited

Engineering Contradiction:
Improvecompositional profile controlVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The manufacturing process segments the optical ceramic production into multiple thin layers, each with controlled dopant concentrations. By building the ceramic layer-by-layer with varying dopant levels, the method achieves three-dimensional compositional profiles and smoothly varying gradients that cannot be obtained through conventional bulk sintering or diffusion bonding techniques.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from conventional two-dimensional or one-dimensional dopant distribution to full three-dimensional compositional control. By controlling dopant concentration in the x, y, and z directions through layered deposition, the method creates truly three-dimensional compositional profiles including radial and axial gradients that are impossible with traditional methods.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Ease of manufacture

If uniform dopant distribution is achieved through conventional methods, then manufacturing is simpler, but thermal lensing, beam distortion, and thermal stress fracture occur due to non-uniform temperature distribution

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidthermal stress resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

Instead of uniform dopant distribution throughout the optical ceramic, the invention applies local quality by varying dopant concentrations at different locations and depths. Each layer receives a specific dopant concentration tailored to its position, creating spatially varying compositional profiles that enable localized thermal management and reduce thermal stress concentrations.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The method changes the dopant concentration parameter as a function of position and layer depth. By systematically varying dopant levels across different layers and positions, the invention creates compositional gradients that modify thermal and optical properties locally, reducing thermal lensing and beam distortion while maintaining manufacturing feasibility.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If segmented optical ceramics are joined through diffusion bonding to achieve dopant gradients, then compositional variation is obtained, but the process is complex and cannot achieve smoothly varying three-dimensional profiles

Engineering Contradiction:
Improvecompositional gradient controlVSAvoidmanufacturing efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The invention performs preliminary action by pre-distributing dopants during the layer deposition stage rather than relying on post-assembly diffusion bonding. Each layer is deposited with its final dopant concentration already in place, eliminating the need for complex diffusion bonding processes and enabling direct formation of three-dimensional compositional profiles in a single manufacturing sequence.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of optical ceramics with uniform dopant profiles, reducing thermal lensing, beam distortion, and thermal stress fracture, while enhancing manufacturing yield and reducing costs, resulting in improved thermal management and device performance.

Implementation Method 1

using micro-deposition techniques such as electrostatic or electro-photographic deposition

Methodology Applied
Scientific EffectElectrostatic deposition: Electrostatic Deposition

Implementation Method 2

using micro-deposition techniques such as electrostatic or electro-photographic deposition

Methodology Applied
Scientific EffectElectro-photographic deposition: Electrophoretic Deposition

Implementation Method 3

binding the first and second optical material powders of each thin layer to each other and each thin layer with an adjacent layer such that a green state optical ceramic is produced

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 4

densifying the green state optical ceramic to obtain the optical ceramic

Methodology Applied
Scientific EffectHot isostatic pressing: Hot Isostatic Pressing

Data Source

PatentUS9388086B2Method of fabricating optical ceramics containing compositionally tailored regions in three dimension
Publication Date: 2016.07.12 RAYTHEON CO
  • US9388086B2 patent drawing
  • US9388086B2 patent drawing
  • US9388086B2 patent drawing

AI summary

In accordance with the present embodiment, a method for making an optical ceramic comprises depositing a plurality of thin layers of powder. The powder comprises a first optical material powder having a first dopant level, and a second optical material powder. The first and second optical material powders are deposited for each layer based on the first dopant level and according to data associated with a three-dimensional (3D) compositional profile design of an optical ceramic. The method further comprises binding the first and second optical material powders of each thin layer to each other and each thin layer with an adjacent layer such that a green state optical ceramic is produced based on the 3D compositional profile design. The method further comprises densifying the green state optical ceramic to obtain the optical ceramic.