Optical Dissolved Oxygen Measurement via Luminescence

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Solution Overview

Problem

Existing methods for measuring dissolved oxygen in organic liquids often require direct contact with the liquid, which can lead to contamination and damage, or require adding chemicals that adversely affect the liquid's properties.

Innovation Solution

A method and apparatus that induce luminescence of dissolved oxygen in a liquid using optical radiation at a wavelength conforming to the oxygen's absorption band, allowing for the analysis of detected luminescent light to determine oxygen concentrations without direct contact or chemical addition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If direct contact methods (probes, membranes) are used to measure dissolved oxygen, then measurement capability is achieved, but contamination of the liquid and damage to components occur

Engineering Contradiction:
Improvedissolved oxygen measurementVSAvoidcontamination and damage
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent introduces optical radiation as an intermediary to transfer energy to dissolved oxygen molecules, enabling measurement without physical contact. The optical system acts as a mediator that conveys measurement information through light interaction, eliminating the need for direct contact between measurement components and the liquid, thus preventing contamination and component damage

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces mechanical contact-based measurement systems (probes, membranes) with an optical measurement system. By substituting mechanical interaction with optical radiation interaction, the system achieves dissolved oxygen measurement without physical contact, thereby eliminating contamination and mechanical damage to both the liquid and measurement components

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Measurement precision

If chemicals are added to the liquid for measurement, then measurement capability is achieved, but the liquid's properties are adversely impacted

Engineering Contradiction:
Improvedissolved oxygen measurementVSAvoidliquid properties
Core Design Contradiction:
Measurement precisionVSStability of the object's composition

Solution Approach 1:

The patent uses optical radiation as an intermediary to excite dissolved oxygen molecules, producing luminescence that can be detected to determine oxygen concentration. This approach eliminates the need to add chemicals to the liquid, as the optical system interacts directly with the dissolved oxygen without altering the liquid's chemical composition or properties

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent substitutes chemical addition methods with optical measurement methods. By using optical radiation to induce luminescence in dissolved oxygen, the system achieves measurement without introducing chemicals that would adversely impact the liquid's properties, maintaining the liquid's chemical stability and composition

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables non-invasive and accurate measurement of dissolved oxygen levels in organic liquids, preventing contamination and maintaining the integrity of the liquid's properties.

Implementation Method 1

inducing luminescence of dissolved oxygen in a liquid using optical radiation at a wavelength conforming to the oxygen's absorption band

Methodology Applied
Scientific EffectLuminescence: Luminescence

Implementation Method 2

optical radiation at a wavelength that conforms to a dissolved oxygen absorption band

Methodology Applied
Scientific EffectAbsorption Spectroscopy: Absorption Spectroscopy

Implementation Method 3

a photodetector that is located outside of the container but that is in optical communication with the interior of the container

Methodology Applied
Scientific EffectPhotoelectric Effect: Photoelectric Effect

Data Source

PatentUS12216046B2Measurement of dissolved oxygen using optical radiation induced luminescence
Publication Date: 2025.02.04 YOKOGAWA ELECTRIC CORP
  • US12216046B2 patent drawing
  • US12216046B2 patent drawing
  • US12216046B2 patent drawing

AI summary

Methods and apparatus for analyzing optical measurements to determine whether a liquid includes dissolved oxygen, to determine a predicted concentration of the dissolved oxygen in the liquid, and/or to determine additional or alternative feature(s) related to dissolved oxygen in the liquid. An optical source can be controlled to emit optical radiation into a container that contains the liquid. The optical source can be located outside of the container, and the optical radiation includes (e.g., is restricted to) radiation that conforms to a dissolved oxygen absorption band. The optical radiation can be pulsed or can be periodically intensity modulated. A photodetector, located outside of the container but in optical communication with the interior of the container, can generate the optical measurements used in the analysis.