Optical Element Coating with Discontinuous Pressure and Layer Segmentation

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Solution Overview

Problem

Conventional optical elements with water-repellent films, while improving wear resistance, do not provide sufficient antiweatherability, especially when used in severe exterior conditions such as vehicle-mounted view cameras, lacking favorable light resistance.

Innovation Solution

A manufacturing method for an optical element involving a stack of layers with a silicon oxide-containing layer formed prior to a fluorine compound-containing layer, utilizing a discontinuous pressure condition to enhance both antiweatherability and abrasion resistance, where the fluorine compound-containing layer has a surface with bumps and dents for improved adherence and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a water-repellent film with fluorine atoms is formed on the optical element, then wear resistance is improved, but antiweatherability and light resistance deteriorate

Engineering Contradiction:
Improvewear resistanceVSAvoidantiweatherability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The coating is divided into multiple functional layers: a base layer (silicon oxide-containing layer) providing antiweatherability and light resistance, and a top layer (fluorine compound-containing layer) providing wear resistance and water repellency. This segmentation allows each layer to perform its specific function without compromising the others.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The silicon oxide-containing layer is formed first as a preliminary step before forming the fluorine compound-containing layer. This preliminary action ensures that the base layer with good antiweatherability is established before applying the wear-resistant fluorine layer, preventing the fluorine layer from directly contacting the optical element surface.

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If a single-layer fluorine coating is applied, then water repellency is achieved, but both abrasion resistance and light resistance cannot be simultaneously improved

Engineering Contradiction:
Improvewater repellencyVSAvoidabrasion resistance and light resistance
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The invention uses a composite coating structure combining silicon oxide-containing layer and fluorine compound-containing layer. This composite material approach allows the coating to exhibit multiple properties: the silicon oxide layer contributes to hardness, abrasion resistance, and light resistance, while the fluorine layer provides water repellency and low friction.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If continuous pressure condition is used during layer formation, then manufacturing process is simplified, but surface quality and layer adhesion deteriorate

Engineering Contradiction:
Improveprocess simplicityVSAvoidsurface quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The pressure condition is made discontinuous during the coating formation process, with periodic variations in pressure during deposition. This periodic action helps control the deposition rate and improves layer uniformity, surface quality, and adhesion between layers, while still maintaining a relatively simple manufacturing process.

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optical element achieves enhanced antiweatherability and abrasion resistance, maintaining performance under severe conditions with improved light resistance and durability, as demonstrated by tests showing improved contact angles and resistance to abrasion and environmental degradation.

Implementation Method 1

a multi-layers forming step for forming an optical multi-layered part of the stack covering of layers, and an outermost surface forming step for forming an outermost surface part of the stack covering of layers

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS12147012B2Optical element and method for manufacturing the same
Publication Date: 2024.11.19 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US12147012B2 patent drawing
  • US12147012B2 patent drawing
  • US12147012B2 patent drawing

AI summary

There is provided a method for manufacturing an optical element comprising a base material, and a stack covering of layers formed on the base material. The method of the present disclosure comprises a multi-layers forming step for forming an optical multi-layered part of the stack covering, and an outermost surface forming step for forming an outermost surface part of the stack covering. A pressure condition for the formation of the stack covering is made discontinuous between the multi-layers forming step and the outermost surface forming step. In the outermost surface forming step, a silicon oxide-containing layer is formed prior to a formation of a fluorine compound-containing layer.