Optical Element Light-Shielding Film Alkali Resistance Coating

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Solution Overview

Problem

Optical elements, such as lenses, experience color change and development of white spots when used under high-temperature and high-humidity conditions, especially after washing with an alkaline aqueous solution, due to the instability of light-shielding films.

Innovation Solution

The optical element features a light-shielding film with a binder resin, a coloring agent, and inorganic fine particles, along with a protective coating comprising a cured mixture of melamine or benzoguanamine resin and phenolic resin, which enhances waterproofness and alkali resistance, preventing color change and white spots.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a light-shielding film with dye is used on the optical element, then the optical element can prevent flares and ghosts, but the light-shielding film changes color and develops white spots when used under high-temperature and high-humidity conditions, especially after washing with alkaline aqueous solution

Engineering Contradiction:
Improveflare preventionVSAvoidappearance stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

A protective coating layer is introduced as an intermediary between the light-shielding film and the external environment (alkaline solutions and humidity). This coating acts as a barrier that prevents direct contact between the dye-containing light-shielding film and harmful external factors, thereby preventing color change and white spot formation while maintaining the flare prevention function

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The optical element structure is transformed into a composite material system consisting of multiple layers: the light-shielding film layer containing dye, and the protective coating layer. This composite structure combines the light-shielding function of the dye-containing film with the protective function of the coating, resolving the contradiction between flare prevention and appearance stability

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If the optical element is washed with alkaline aqueous solution after forming the light-shielding film and protective coating, then cleaning effectiveness is improved, but the light-shielding film develops white spots and color changes

Engineering Contradiction:
Improvecleaning effectivenessVSAvoidfilm stability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The protective coating serves as an intermediary barrier that allows the light-shielding film to be exposed to alkaline cleaning solutions without direct harmful interaction. The coating withstands the alkaline environment and prevents it from penetrating to the dye-containing film, enabling effective cleaning while maintaining film stability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The protective coating is applied in advance before the cleaning process, providing a cushioning protective layer that pre-shields the light-shielding film from the damaging effects of alkaline solutions. This prior protection prevents the white spot formation and color changes that would otherwise occur during cleaning

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution maintains the optical element's appearance over a long period under high-temperature and high-humidity conditions, even after exposure to alkaline solutions, by ensuring the light-shielding film's stability and adhesion.

Implementation Method 1

this protective coating prevents dyes in a light-shielding film, such as a black dye, from dissolving out of the film

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

a protective coating comprising a cured mixture of melamine or benzoguanamine resin and phenolic resin, which enhances waterproofness and alkali resistance

Methodology Applied
Scientific EffectChemical resistance:

Data Source

PatentEP3026469B1Optical element and method for producing optical element
Publication Date: 2023.01.11 CANON KK
  • EP3026469B1 patent drawingFigure 1
  • EP3026469B1 patent drawingFigure 2A~2E
  • EP3026469B1 patent drawing

AI summary

An optical element (1) having a substrate (2) and a light-shielding film (3) on part of an outer portion of the substrate (2) further contains a coating (4) on the light-shielding film (3), the coating (4) containing a cured mixture of melamine or benzoguanamine resin, and a phenolic resin, in proportions by mass of 1:5 to 7:5.