Optical Resin Composition Refractive Index Adjustment Compatibility

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Solution Overview

Problem

Conventional optical resin compositions with fluorine-containing resins and refractive index modifiers suffer from compatibility issues, leading to degraded transparency and the need for refractive index adjustment during high-temperature processing, which challenges the production of optical members with high thermal resistance.

Innovation Solution

An optical resin composition incorporating a fluorine-containing resin and a refractive index modifier, where the refractive index modifier consists of 95% or more of a linear polymer with specific repeating units based on fluorine-containing ethylene-based monomers, ensuring improved compatibility and solubility, allowing for high-temperature processing without transparency degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a conventional refractive index modifier is mixed with fluorine-containing resin, then the refractive index can be adjusted, but compatibility is poor leading to degraded transparency

Engineering Contradiction:
Improverefractive index adjustmentVSAvoidtransparency
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the molecular weight parameter of the refractive index modifier to a specific range (500-5000) and uses fluorine-containing ethylene-based monomers with specific structures, transforming the physical and chemical properties of the modifier to achieve both transparency and refractive index adjustability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite system by combining fluorine-containing resin with specifically designed fluorine-containing oligomers and polymers as refractive index modifiers, where the composite structure ensures compatibility while achieving the desired optical properties

Inventive Principle:
Principle #40Composite materials

2Temperature

If fluorine-containing resin with high glass transition temperature is used to achieve high thermal resistance, then thermal resistance is improved, but high-temperature processing degrades transparency

Engineering Contradiction:
Improvethermal resistanceVSAvoidtransparency during processing
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The fluorine-containing oligomer and polymer act as intermediary substances between the high glass transition temperature resin and the processing conditions, providing a buffer that maintains compatibility and transparency during high-temperature processing while preserving the thermal resistance of the base resin

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent adjusts the molecular weight and chemical structure parameters of the refractive index modifier to specifically counteract the degradation effects of high-temperature processing, ensuring that transparency is maintained even when processing resins with high glass transition temperatures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition maintains high transparency and thermal resistance, enabling refractive index adjustment within a desired range, even during high-temperature processing, thus addressing compatibility and thermal resistance challenges.

Implementation Method 1

a problem with compatibility between the fluorine-containing resin and the refractive index modifier arises, that is, a problem arises that the refractive index modifier is not uniformly mixed with the fluorine-containing resin

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 2

a refractive index distribution is formed by diffusing a refractive index modifier in an optical resin composition in which the refractive index modifier is added to the fluorine-containing resin

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS20240141080A1Optical resin composition and optical resin formed body
Publication Date: 2024.05.02 NITTO DENKO CORP
  • US20240141080A1 patent drawing
  • US20240141080A1 patent drawing
  • US20240141080A1 patent drawing

AI summary

An optical resin composition of the present invention includes fluorine-containing resin and a refractive index modifier. The optical resin composition satisfies the following matter (a) or (b): (a) the refractive index modifier includes 95 mass % or more of a linear polymer (A) including repeating units based on a fluorine-containing ethylene-based monomer such that the number of the repeating units is 5, and a proportion of a content of the linear polymer (A) in the optical resin composition is 1 mass % or more and less than 15 mass %; (b) the refractive index modifier includes 95 mass % or more of a linear polymer (B) including repeating units based on a fluorine-containing ethylene-based monomer such that the number of the repeating units is 6, and a proportion of a content of the linear polymer (B) in the optical resin composition is 1 mass % or more and less than 13 mass %.