Optical Sheet Coextrusion for Fine Structure Transfer

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Solution Overview

Problem

Existing methods for manufacturing optical sheets by melt extrusion molding face challenges in transferring fine uneven structures to thin sheets due to rapid cooling and adhesion issues, leading to curled or peeled layers and compromised external appearance.

Innovation Solution

A method involving coextrusion molding of a polycarbonate resin and an amorphous polyamide resin, with a glass transition temperature difference of ±40°C, to create a layered structure with a fine uneven shape, allowing for improved heat retention and peeling without curling, and using a metal rigid or elastic roll for pressure contact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the set temperature of the die or roll is raised to improve transferability of fine uneven structure, then the transferability improves, but the thermoplastic resin is not cooled sufficiently quickly and adheres to the shaping cooling roll causing peeling marks

Engineering Contradiction:
Improvetransferability of fine uneven structureVSAvoidpeeling marks on external appearance
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The invention divides the resin sheet into multiple layers with different thermal properties. The first layer (higher heat capacity) is positioned at the air gap side to retain heat and prevent premature solidification, while the second layer (lower heat capacity) is at the roll contact side to enable sufficient cooling and prevent adhesion. This segmentation resolves the contradiction between maintaining heat for transferability and enabling cooling to prevent peeling marks.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the resin sheet are assigned different thermal characteristics through layering. The first layer has higher heat capacity for heat retention in the air gap region, while the second layer has lower heat capacity for efficient heat dissipation at the roll contact region. This local differentiation of thermal properties allows simultaneous achievement of high transferability and prevention of peeling marks.

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If the contact pressure is increased to improve transferability, then the transferability improves, but roll bending occurs making it difficult to control thickness and transfer uniformly

Engineering Contradiction:
Improvetransferability of fine uneven structureVSAvoidroll bending and thickness uniformity
Core Design Contradiction:
Manufacturing precisionVSShape

Solution Approach 1:

The invention performs preliminary action by increasing the sheet thickness through layering before the pressure contact step. The multi-layer structure provides sufficient heat capacity and structural integrity at moderate pressures, enabling high transferability without requiring excessive contact pressure that would cause roll bending. This preliminary thickening through coextrusion allows uniform pressure distribution.

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If a polyolefin-based resin with high crystallinity is used for the protective film layer, then the ease of peeling improves, but the sheet is easily curled due to difference in volume shrinking amount between layers

Engineering Contradiction:
Improveease of peelingVSAvoidsheet curling
Core Design Contradiction:
Ease of operationVSShape

Solution Approach 1:

The invention changes the material parameter from crystalline polyolefin to amorphous resin for the first layer. Amorphous resins exhibit minimal volume shrinkage upon cooling, preventing curling caused by differential shrinkage between layers.同时,the first layer is designed to be peelable from the second layer, maintaining ease of separation while eliminating the curling problem through material selection.

Inventive Principle:
Principle #35Parameter changes

4Manufacturing precision

If the resin is molded at high temperature to improve transferability, then the transferability improves, but the resin is decomposed and external appearance is adversely influenced

Engineering Contradiction:
Improvetransferability of fine uneven structureVSAvoidresin decomposition and external appearance defects
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The invention segments the resin sheet into multiple layers with different thermal capacities. The first layer acts as a heat reservoir, maintaining elevated temperature longer during the pressure contact period to ensure high transferability, while the second layer provides thermal management. This allows sufficient heat retention without requiring excessively high molding temperatures that would cause decomposition.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the transferability of fine uneven structures while maintaining a good external appearance by preventing rapid cooling and ensuring the layers can be easily peeled, resulting in a thin, high-functional optical sheet with improved luminance and viewing angle.

Implementation Method 1

the first layer and the second layer are layered by coextrusion molding... improves heat retention

Methodology Applied
Scientific EffectHeat retention: Thermal Insulation

Implementation Method 2

the polycarbonate resin contained in the first layer and the amorphous polyamide resin contained in the second layer have a glass transition temperature difference in the range of ±40°C

Methodology Applied
Scientific EffectGlass transition: Phase Change

Data Source

PatentEP2983017B1Optical sheet and method for manufacturing same
Publication Date: 2021.05.26 MITSUBISHI GAS CHEM CO INC
  • EP2983017B1 patent drawingFigure 1~3
  • EP2983017B1 patent drawingFigure 4~5

AI summary

A method for manufacturing an optical sheet capable of sufficiently improving transferability of a fine uneven structure, and an optical sheet manufactured by molding by use of the method, are provided. The optical sheet according to the present invention includes a first layer containing a polycarbonate resin and a second layer containing an amorphous polyamide resin, the first layer and the second layer being layered by coextrusion molding. The first layer and the second layer are peelable from each other; and a surface of at least one of the first layer and the second layer has a fine uneven shape formed thereat. Such an optical sheet including a plurality of layers can make the entirety sheet thick at the time of melt extrusion molding, and therefore the layered body during the molding can hold a sufficient amount of heat. This improves the transferability of the fine uneven structure. In addition, the layers may be peeled off so that one of the layers is used. In this case, the optical sheet can be made thinner.