Organic Buffer Layer for Emissive Device Stress Relief

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Solution Overview

Problem

Organic electroluminescent (EL) devices face challenges in preventing moisture and oxygen penetration, leading to degradation and reduced lifetime, especially with larger screen sizes and thinner designs, where traditional sealing methods fail to completely prevent water and oxygen ingress, causing defects like detachment or cracks in the gas barrier layer.

Innovation Solution

The implementation of a multi-layer structure comprising a substrate, first and second electrodes, organic function layers, inorganic layers, an organic buffer layer, and a gas barrier layer, where the first inorganic layer with a lower elastic modulus than the second inorganic layer relieves external forces, and the organic buffer layer with a specific elastic modulus and thickness configuration helps prevent defects, while the gas barrier layer ensures water and oxygen prevention.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Weight of stationary object

If a thin film structure is used to reduce weight and thickness, then the weight and thickness are reduced, but the gas barrier properties deteriorate and water penetration increases

Engineering Contradiction:
Improveweight of organic EL deviceVSAvoidgas barrier properties
Core Design Contradiction:
Weight of stationary objectVSReliability

Solution Approach 1:

The patent employs a composite sealing structure consisting of multiple layers including an organic buffer layer, an inorganic protective layer, and a gas barrier layer. This multi-material composite approach combines the advantages of different materials: the organic layer provides flexibility and stress relief, while the inorganic layers provide rigid protection and gas barrier properties, thereby maintaining reliability while reducing overall thickness and weight compared to traditional single-material sealed structures.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements a nested multi-layer structure where the organic buffer layer is positioned beneath the inorganic protective layer, which in turn is beneath the gas barrier layer. This nested arrangement allows each layer to perform its specific function while contributing to the overall sealing performance, enabling thin-film design without compromising gas barrier properties.

Inventive Principle:
Principle #7Nested doll (Nesting)

2Area of stationary object

If the screen size is increased, then the display area is enlarged, but the prevention of water and oxygen permeation becomes more difficult

Engineering Contradiction:
Improvescreen areaVSAvoidwater and oxygen permeation
Core Design Contradiction:
Area of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The composite sealing structure with organic buffer layer, inorganic protective layer, and gas barrier layer provides enhanced protection against water and oxygen permeation. This multi-layer composite system maintains effective barrier properties even as the screen area increases, overcoming the limitation of traditional single-layer seals that become less effective with larger surface areas.

Inventive Principle:
Principle #40Composite materials

3Reliability

If a gas barrier layer is formed by high-density plasma film-forming method, then gas barrier properties are improved, but detachment or cracks occur at the periphery or bumps

Engineering Contradiction:
Improvegas barrier propertiesVSAvoidstructural integrity
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The organic buffer layer serves as an intermediary layer between the substrate and the inorganic protective layer. This intermediate layer absorbs and distributes external forces and internal stresses, preventing stress concentration at the periphery and bumps. By acting as a stress-relief mediator, it prevents detachment and cracks in the gas barrier layer while maintaining the high-density plasma-formed film's excellent gas barrier properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The organic buffer layer is formed beforehand to provide cushioning and stress relief before the inorganic protective layer and gas barrier layer are deposited. This pre-cushioning structure prevents future detachment and cracking by already being in place to absorb external forces and internal stresses during subsequent processing and device operation.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

4Strength

If an organic buffer layer is disposed under the gas barrier layer to prevent cracks, then structural integrity is improved, but external forces cause detachment or cracks in the cathode layer

Engineering Contradiction:
Improvestructural integrityVSAvoidcathode layer integrity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent uses a composite structure with both organic and inorganic layers to protect the cathode. The inorganic protective layer provides rigid support and distributes external forces, while the organic buffer layer provides flexibility and stress relief. This composite approach protects the cathode layer from detachment and cracks caused by external forces during buffer layer formation, maintaining both structural integrity and cathode reliability.

Inventive Principle:
Principle #40Composite materials

Data Source

PatentUS8164258B2Emissive device having a layer that relieves external forces on adjacent layer, process for producing the emissive device and an electronic apparatus including the emissive device
Publication Date: 2012.04.24 SEIKO EPSON CORP
  • US8164258B2 patent drawing
  • US8164258B2 patent drawing
  • US8164258B2 patent drawing

AI summary

An emissive device includes a substrate; a plurality of first electrodes; pixel banks having a plurality of openings each corresponding to the position of a corresponding one of the first electrodes; organic function layers disposed in at least the openings; a second electrode disposed so as to cover the pixel banks and the organic function layers; a first inorganic layer disposed over the second electrode; a second inorganic layer disposed over the first inorganic layer; an organic buffer layer disposed over the second inorganic layer; and a gas barrier layer disposed over the organic buffer layer.