Organic Capping Layer Material for OLED Light Extraction

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Solution Overview

Problem

Current organic capping layer materials in OLEDs have refractive indices that are too low, limiting their ability to enhance light extraction efficiency and color cast, and often result in high drive voltage and reduced device lifetime.

Innovation Solution

An organic compound with a specific structure, represented by Formula I, is used as an organic capping layer material, which includes a high-refractive-index layer to improve light extraction and reduce drive voltage, and is synthesized using palladium catalysts and specific ligands to achieve high current efficiency and long device lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If conventional organic capping layer materials with refractive index 1.75-1.95 are used, then the device structure is simple and materials are easy to obtain, but the light extraction efficiency is insufficient and color cast cannot be improved

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidmaterial availability
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent changes the refractive index parameter of the capping layer material from the conventional 1.75-1.95 range to a higher range of 2.0-2.2, which significantly improves light extraction efficiency and color cast performance while maintaining material synthesizability through established chemical methods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite molecular structures combining specific aromatic hydrocarbon frameworks with electron-withdrawing groups, creating materials that achieve both high refractive index and good processability, resolving the contradiction between performance and manufacturability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If high refractive index organic capping layer materials are used to improve light extraction efficiency, then color cast improves, but drive voltage increases and device lifetime decreases

Engineering Contradiction:
Improvecolor castVSAvoiddevice lifetime
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent introduces electron-withdrawing groups at specific positions on the aromatic hydrocarbon framework, creating localized electron-deficient regions that optimize charge transport and reduce drive voltage while maintaining the high refractive index needed for color cast improvement

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent optimizes molecular parameters including HOMO-LUMO energy gap and carrier mobility by adjusting substituent positions and types, achieving a balance where drive voltage is reduced and device lifetime is extended while maintaining improved color cast

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20240217916A1Organic compound and use thereof
Publication Date: 2024.07.04 WUHAN TIANMA MICRO ELECTRONICS CO LTD
  • US20240217916A1 patent drawing
  • US20240217916A1 patent drawing
  • US20240217916A1 patent drawing

AI summary

Provided are an organic compound and use thereof, where the organic compound has a structure represented by Formula I. The use of organic compound as a material of the capping layer in combination with a capping layer material containing high-refractive-index small organic molecules is conducive to improving the efficiency of a device, in particular improving the color cast.