Organic Compound for Blue Light-Emitting Device Driving Voltage

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Solution Overview

Problem

Current light-emitting devices face challenges in achieving low driving voltage and high external quantum efficiency, particularly in emitting blue light effectively.

Innovation Solution

A light-emitting device incorporating an organic compound represented by Formula 1, which includes specific structural elements allowing for improved hole and electron transport, is used. This compound is integrated into the interlayer and emission layer, enhancing the device's efficiency and reducing driving voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional organic compounds are used in light-emitting devices, then the device structure is simple, but the driving voltage remains high and external quantum efficiency is low

Engineering Contradiction:
Improveexternal quantum efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent employs composite organic compounds that integrate multiple functional moieties within a single molecular structure. Specifically, the compounds combine electron-transport groups (such as triazine or pyrimidine rings), hole-transport groups (such as carbazole or triphenylamine), and blue-light-emitting groups (such as boronate or BPhen) into unified structures. This composite approach enables simultaneous optimization of electron transport, hole transport, and light emission functions, thereby achieving high external quantum efficiency and low driving voltage without requiring multiple separate material layers, thus resolving the contradiction between performance improvement and structural complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The organic compounds disclosed in the patent are designed to perform multiple functions simultaneously: electron transport, hole transport, and blue light emission. This multi-functionality is achieved by incorporating electron-transport units (e.g., triazine, pyrimidine), hole-transport units (e.g., carbazole, triphenylamine), and emitting units (e.g., boronate, BPhen) within the same molecular framework. As a result, a single compound layer can replace multiple functional layers, simplifying device structure while maintaining high efficiency and low driving voltage, thus resolving the technical contradiction.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Illumination intensity

If conventional organic compounds are used, then manufacturing is easier, but blue light emission efficiency is insufficient

Engineering Contradiction:
Improveblue light emission efficiencyVSAvoidcompound synthesis difficulty
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent applies segmentation by dividing the organic compound into distinct functional modules: electron-transport units (e.g., triazine, pyrimidine rings), hole-transport units (e.g., carbazole, triphenylamine groups), and blue-light-emitting units (e.g., boronate, BPhen structures). These modular units can be independently synthesized and then coupled through well-established organic synthesis methods. This segmentation strategy enables precise control over each function's optimization while maintaining overall molecular synthesizability, thus achieving high blue light emission efficiency without excessive manufacturing difficulty.

Inventive Principle:
Principle #1Segmentation

3Productivity

If high efficiency compounds are used, then external quantum efficiency improves, but driving voltage remains high

Engineering Contradiction:
Improveexternal quantum efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSPower

Solution Approach 1:

The patent utilizes parameter changes by systematically adjusting key molecular parameters including: (1) introducing electron-deficient groups (triazine, pyrimidine) to enhance electron affinity and improve electron transport, thereby reducing electron injection barrier and driving voltage; (2) incorporating electron-rich groups (carbazole, triphenylamine) to improve hole transport capability; (3) optimizing the balance between electron and hole transport properties to achieve efficient carrier recombination and high external quantum efficiency. By carefully tuning these molecular parameters, the patent simultaneously achieves low driving voltage and high efficiency, resolving the technical contradiction.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organic compound in the light-emitting device results in a lower driving voltage and improved external quantum efficiency, specifically optimizing blue light emission.

Implementation Method 1

Holes injected from the first electrode may move to the emission layer through the hole transport region

Methodology Applied
Scientific EffectHole transport:

Implementation Method 2

Electrons injected from the second electrode may move to the emission layer through an electron injection layer in the electron transport region

Methodology Applied
Scientific EffectElectron transport:

Implementation Method 3

Carriers such as holes and electrons may combine in the emission layer to produce excitons

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 4

As excitons move/relax from an excited state to a ground state, light may be generated

Methodology Applied
Scientific EffectLight emission: Luminescence

Data Source

PatentUS20240334812A1Organic compound, and light-emitting device and electronic apparatus including the same
Publication Date: 2024.10.03 SAMSUNG DISPLAY CO LTD
  • US20240334812A1 patent drawing
  • US20240334812A1 patent drawing
  • US20240334812A1 patent drawing

AI summary

A light-emitting device includes a first electrode, a second electrode facing the first electrode, an interlayer between the first electrode and the second electrode and including an emission layer, and an organic compound represented by Formula 1.