Organic Compound for OLED Electron Transport and Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing organic light emitting diodes face challenges in achieving excellent lifespan, efficiency, and stability due to inefficient electron mobility and material crystallization caused by Joule heat, necessitating a compound with enhanced electron injection properties and electrochemical stability.

Innovation Solution

A compound for organic optoelectronic devices, represented by specific chemical formulas, is introduced, which acts as a light emitting or electron injection and transport material, and host with a dopant, improving electron mobility and stability, and is incorporated into various organic thin layers within the OLED structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional organic materials are used in OLED, then device structure can be maintained, but electron mobility is insufficient and material crystallization occurs due to Joule heat

Engineering Contradiction:
Improveelectron mobilityVSAvoidmaterial stability
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent introduces novel organic compounds with specific molecular structures (Formulae 1 and 2) that fundamentally change the material parameters including electron mobility, thermal stability, and electrochemical stability. These parameter changes enable the material to maintain amorphous state at operating temperatures while providing sufficient electron transport capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategies by combining specific molecular components (e.g., dibenzofuran, dibenzodioxole, carbazole groups) to create new organic compounds that exhibit synergistic properties. The compounds integrate multiple functional groups that collectively provide both high electron mobility and thermal stability, resolving the contradiction between speed and reliability

Inventive Principle:
Principle #40Composite materials

2Duration of action of moving object

If existing organic materials are used, then device manufacturing can proceed, but lifespan and efficiency are insufficient

Engineering Contradiction:
Improvedevice lifespanVSAvoiddevice efficiency
Core Design Contradiction:
Duration of action of moving objectVSProductivity

Solution Approach 1:

The patent achieves improved lifespan and efficiency by changing the chemical and physical parameters of the organic material. The new compounds exhibit enhanced electrochemical stability (wider operating voltage range) and thermal stability (higher glass transition temperature), which directly extend device lifespan while maintaining or improving efficiency through better electron transport

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops organic compounds that can be deposited as thin films using conventional vacuum deposition techniques, replacing materials that require complex multi-layer structures. The new materials achieve superior performance with simpler, more durable single-layer or few-layer configurations, effectively making the device structure more resilient rather than disposable

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If conventional materials are used, then OLED can operate, but driving voltage remains high and electrochemical stability is insufficient

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoiddriving voltage
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent changes the electrochemical parameters of the organic material by introducing compounds with optimized HOMO-LUMO energy levels. The new materials exhibit wider electrochemical stability windows and lower operating voltages due to their specific molecular structures, simultaneously improving reliability and reducing power consumption

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enhances the lifespan, efficiency, and thermal stability of organic light emitting diodes by optimizing electron transport and injection, reducing driving voltage, and maintaining electrochemical stability during operation.

Implementation Method 1

a voltage or a current is applied to at least two electrodes to inject holes and/or electrons into an organic material semiconductor positioned at an interface of the electrodes, and the device is driven by the injected electrons and holes

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

Such an organic light emitting diode converts electrical energy into light by applying a current to an organic light emitting material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

a phosphorescent material emits lights by transporting the electrons from a ground state to an exited state, non-radiance transiting of a singlet exciton to a triplet exciton through intersystem crossing, and transiting a triplet exciton to a ground state to emit light

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 4

requiring a compound with enhanced electron injection properties and electrochemical stability

Methodology Applied
Scientific EffectThermal stability: Thermal Expansion

Data Source

PatentUS10892422B2Compound for organic optoelectronic device, organic light emitting diode including the same, and display including the organic light emitting diode
Publication Date: 2021.01.12 SAMSUNG ELECTRONICS CO LTD
  • US10892422B2 patent drawing
  • US10892422B2 patent drawing
  • US10892422B2 patent drawing

AI summary

A compound for an organic optoelectronic device represented by Chemical Formula 1:wherein groups X1 to X8, Y1, Y2, L1, L2, Ar1, Ar2, and variables m1, m2, n1, and n2 are described in the specification.