Organic Compound for OLED Charge Mobility and Stability

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Solution Overview

Problem

Current organic light emitting diodes (OLEDs) face challenges in achieving high efficiency and long lifespan due to limitations in hole and electron mobility and electrochemical stability, particularly for large-size flat panel displays.

Innovation Solution

An organic compound represented by Chemical Formula 1, featuring fused heteroaryl groups with sulfur and oxygen atoms, and a heteroaryl group with nitrogen, is used to enhance charge mobility, reduce driving voltage, and balance hole and electron flow, thereby improving the efficiency and lifespan of OLEDs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic materials are used in OLEDs, then device structure and manufacturing process are simpler, but charge mobility is insufficient and electrochemical stability is poor

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidmolecular structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite molecular structures combining heteroaryl groups (containing N, O, S atoms) with aromatic hydrocarbon groups. This composite approach creates materials that simultaneously achieve high charge mobility and electrochemical stability without requiring overly complex device structures or manufacturing processes. The heteroaryl components provide electrochemical stability while the aromatic hydrocarbon components facilitate charge transport.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent systematically varies molecular parameters including the types of heteroatoms (N, O, S), the size and substitution patterns of aromatic hydrocarbon groups, and the overall molecular geometry. By optimizing these parameters, the invention achieves high charge mobility and electrochemical stability within a manageable structural complexity range, resolving the contradiction between performance and complexity.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If organic materials with high charge mobility are developed, then OLED efficiency improves, but electrochemical stability deteriorates

Engineering Contradiction:
ImproveOLED efficiencyVSAvoidelectrochemical stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent uses composite molecular structures where heteroaryl groups (providing electrochemical stability through their aromatic rings with N, O, S atoms) are combined with aromatic hydrocarbon groups (providing high charge mobility). This composite design enables the material to simultaneously achieve high OLED efficiency through improved charge transport and maintain electrochemical stability, directly resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality by assigning different functional roles to different parts of the molecule: heteroaryl segments are positioned to provide electrochemical stability and charge transport pathways, while aromatic hydrocarbon segments provide additional charge mobility. This spatial differentiation of functional properties allows the material to achieve both high efficiency and stability simultaneously.

Inventive Principle:
Principle #3Local quality

3Duration of action of stationary object

If bipolar characteristics are enhanced to balance hole and electron flow, then device lifespan increases, but material design complexity increases

Engineering Contradiction:
ImproveOLED lifespanVSAvoidmaterial design complexity
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent employs composite molecular structures with heteroaryl groups (containing N, O, or S atoms) combined with aromatic hydrocarbon groups. This composite design inherently provides bipolar characteristics by creating molecules that can simultaneously transport both holes and electrons through their delocalized π-electron systems, achieving balanced charge transport and extended OLED lifespan without requiring overly complex material designs.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent designs organic compounds that perform multiple functions simultaneously: the heteroaryl-aromatic hydrocarbon composite structure provides charge transport, electrochemical stability, and bipolar characteristics all in one material. This multi-functionality reduces the need for separate materials for different functions, thereby extending device lifespan without proportionally increasing material design complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS10147891B2Organic compound, organic optoelectronic device, and display device
Publication Date: 2018.12.04 SAMSUNG SDI CO LTD
  • US10147891B2 patent drawing
  • US10147891B2 patent drawing
  • US10147891B2 patent drawing

AI summary

Disclosed are an organic compound represented by Chemical Formula 1, an organic optoelectronic device including the organic compound, and a display device including the organic optoelectronic device.