Novel Organic Compound for OLED Hole Transport Layer

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Solution Overview

Problem

Current hole transport layers in OLEDs, such as those using NPB, exhibit unsatisfactory luminescent properties, necessitating the development of new compounds with improved luminescent characteristics for enhanced efficiency and reduced power consumption, particularly in mobile applications.

Innovation Solution

A novel organic compound with specific structural features, represented by Formula (1), is introduced, which can be used as a hole transport material, offering improved luminescent properties and efficiency compared to traditional NPB-based materials. This compound is synthesized through methods like the Stetter reaction and Suzuki coupling, and can be incorporated into OLED devices as a charge transport or hole transport layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional NPB-based hole transport layers are used in OLEDs, then the device structure is simple and manufacturing is straightforward, but the luminescent properties are unsatisfactory and luminous efficiency is low

Engineering Contradiction:
Improveease of manufactureVSAvoidluminous efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent modifies the molecular structure parameters of hole transport materials by introducing specific substituents (triphenylamine, carbazole, indole groups) and adjusting molecular weight, glass transition temperature, and HOMO/LUMO energy levels to achieve improved luminescent properties while maintaining manufacturability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite hole transport materials combining multiple functional groups (triphenylamine, carbazole, indole) within single molecular structures to achieve synergistic effects that improve both luminous efficiency and device performance

Inventive Principle:
Principle #40Composite materials

2Device complexity

If traditional NPB-based hole transport layers are used in OLEDs, then the material selection is simple, but power consumption is high due to insufficient luminous efficiency

Engineering Contradiction:
Improvedevice complexityVSAvoidpower consumption
Core Design Contradiction:
Device complexityVSUse of energy by moving object

Solution Approach 1:

The patent optimizes key material parameters including glass transition temperature (Tg > 100°C for stability), HOMO level (5.0-6.0 eV for proper hole injection), and molecular weight to balance device simplicity with reduced power consumption through improved luminous efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups at strategic positions in the molecular structure to enhance local electron-hole recombination efficiency and luminescent properties without fundamentally changing the overall device architecture

Inventive Principle:
Principle #3Local quality

3Productivity

If new organic compounds with improved luminescent properties are developed, then luminous efficiency increases and power consumption decreases, but the chemical synthesis process becomes more complex

Engineering Contradiction:
Improveluminous efficiencyVSAvoidchemical synthesis complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent designs molecular structures as assemblies of well-defined functional modules (triphenylamine core, carbazole substituents, indole groups) that can be synthesized through standardized coupling reactions, making the synthesis process systematic rather than arbitrarily complex

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent develops a universal synthetic platform using common coupling reactions (Stetter, Suzuki) and building blocks that can produce multiple different hole transport materials with varying properties from the same methodological framework

Inventive Principle:
Principle #6Universality (Multi-functionality)

Data Source

PatentUS10294203B2Organic compound and electronic device comprising an organic layer comprising the organic compound
Publication Date: 2019.05.21 DOW GLOBAL TECHNOLOGIES LLC
  • US10294203B2 patent drawing
  • US10294203B2 patent drawing
  • US10294203B2 patent drawing

AI summary

An organic compound suitable for organic layers of electronic devices that show improved luminescent properties.