Organic Compound for Low Voltage OLEDs

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Solution Overview

Problem

Current display devices, particularly organic light-emitting devices, face challenges in achieving high resolution, low driving voltage, and low power consumption while maintaining heat resistance and reliability.

Innovation Solution

Development of a novel organic compound represented by General Formula (G1) with specific structural features that act as a carrier-transport or hole-transport material, enabling efficient hole injection and transport, and providing a deep highest occupied molecular orbital (HOMO) level for low driving voltage and high-temperature reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional organic compounds are used in light-emitting devices, then the device can operate, but the driving voltage is high and power consumption is high

Engineering Contradiction:
Improvepower consumptionVSAvoiddriving voltage stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by introducing specific substituents (e.g., fluorine atoms, electron-withdrawing groups) to change the HOMO level parameter. This parameter change enables lower driving voltage while maintaining device reliability, directly resolving the contradiction between power consumption and voltage stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite organic compounds combining electron-transporting moieties with hole-transporting moieties in a single molecular structure. This composite approach allows the material to simultaneously optimize charge transport properties and energy levels, achieving both low power consumption and stable operation.

Inventive Principle:
Principle #40Composite materials

2Temperature

If conventional organic compounds are used, then the device can be fabricated, but heat resistance is insufficient for high-temperature operation

Engineering Contradiction:
Improveheat resistanceVSAvoidoperation stability
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent changes the thermal stability parameter by incorporating rigid aromatic cores and extending conjugated systems in the molecular structure. These structural modifications increase the glass transition temperature and thermal decomposition temperature, enabling high-temperature operation while maintaining device reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses stable, commercially available aromatic building blocks and standard organic synthesis methods to create thermally stable compounds. This approach achieves high heat resistance through molecular design rather than requiring exotic or expensive materials, making the solution both effective and manufacturable.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Power

If novel organic compounds with specific structures are developed, then low driving voltage and low power consumption are achieved, but the complexity of material synthesis increases

Engineering Contradiction:
Improvedriving voltageVSAvoidsynthesis complexity
Core Design Contradiction:
PowerVSEase of manufacture

Solution Approach 1:

The patent designs organic compounds as modular structures consisting of distinct functional units (electron-transporting groups, hole-transporting groups, linking units) that can be independently synthesized and then coupled together. This segmentation allows chemists to use well-established synthetic methods for each module and assemble the final compound through standard coupling reactions, managing synthesis complexity while achieving the desired electronic properties for low driving voltage.

Inventive Principle:
Principle #1Segmentation

4Manufacturing precision

If high-resolution display devices are developed, then image quality improves, but the requirements for material performance and device precision increase

Engineering Contradiction:
Improvedevice precisionVSAvoidmaterial performance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent introduces specific local structural features (such as fluorine substitution at particular positions, specific substituent groups) into the organic compound molecules to optimize local electronic properties. These localized modifications tune the HOMO level and charge transport characteristics precisely, enabling the material to meet the stringent performance requirements of high-resolution displays without requiring overall structural complexity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic compound results in light-emitting devices with low driving voltage, stable operation under high temperatures, and reduced power consumption, while also being cost-effective and reliable in fabrication.

Implementation Method 1

enabling efficient hole injection and transport

Methodology Applied
Scientific EffectHole transport:

Implementation Method 2

enabling efficient hole injection and transport

Methodology Applied
Scientific EffectHole injection:

Data Source

PatentUS20240132439A1Organic Compound, Light-Emitting Device, and Electronic Device
Publication Date: 2024.04.25 SEMICON ENERGY LAB CO LTD
  • US20240132439A1 patent drawing
  • US20240132439A1 patent drawing
  • US20240132439A1 patent drawing

AI summary

A highly heat-resistant organic compound with favorable hole-transport properties is provided. The organic compound is represented by General Formula (G1). In General Formula (G1), X represents a sulfur atom or an oxygen atom, and R21 to R25 and R27 to R30 each independently represent any one of hydrogen, halogen, a nitrile group, an alkenyl group, a vinyl group, an alkynyl group, an ethynyl group, a straight-chain alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkylsilyl group having 3 to 10 carbon atoms, an aryl group having 6 to 30 carbon atoms, and a heteroaryl group having 2 to 30 carbon atoms. Ar1 represents an aryl group having 6 to 30 carbon atoms or a heteroaryl group having 2 to 30 carbon atoms. Ar2 is represented by General Formula (G1-1).