Organic Dopant for OLED Luminous Efficiency

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Solution Overview

Problem

The development of high-efficiency light emitting materials for large-sized organic light emitting diodes (OLEDs) is hindered by the need for complex compounds containing metals or heavy metals, which are costly and inefficient.

Innovation Solution

A dopant represented by Chemical Formula 1, featuring a chromophore with an electron-withdrawing group substituted electron-donating core, is used to enhance luminous efficiency by reducing the energy gap between singlet and triplet states, allowing for reverse intersystem crossing and high color purity through double chromophores.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If phosphorescent dopants containing heavy metals (iridium, platinum, copper, beryllium) are used to achieve high efficiency light emission, then luminous efficiency is improved, but manufacturing cost increases and device complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidmanufacturing cost
Core Design Contradiction:
Loss of energyVSEase of manufacture

Solution Approach 1:

The patent replaces expensive phosphorescent dopants containing heavy metals (iridium, platinum, copper, beryllium) with a fluorescent dopant having a simple molecular structure. This substitution eliminates the need for costly rare earth metals while maintaining high luminous efficiency through the designed chromophore structure with electron-withdrawing groups and electron-donating cores, directly resolving the contradiction between luminous efficiency and manufacturing cost.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent achieves high luminous efficiency without heavy metals by optimizing molecular parameters of the fluorescent dopant. Specifically, the design incorporates electron-withdrawing groups (W1, W2) and electron-donating cores with specific structural parameters (L1, L2, X1-X16, Z1-Z2, M1-M2) that tune the energy levels and optical properties. This parameter optimization allows the fluorescent dopant to achieve efficiency comparable to phosphorescent materials while avoiding costly heavy metal elements.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If phosphorescent dopants containing heavy metals are used to achieve high efficiency light emission, then luminous efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidcompound complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent simplifies the dopant structure by segmenting the molecular design into functional modules: electron-withdrawing groups (W1, W2) attached to electron-donating cores (L1, L2 with specific heterocyclic structures). This modular segmentation creates a fluorescent dopant with a simpler molecular architecture compared to complex phosphorescent compounds, reducing synthesis difficulty and device complexity while maintaining high luminous efficiency through the coordinated function of these segments.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent replaces complex phosphorescent dopants requiring heavy metals with a simpler fluorescent dopant structure. The fluorescent dopant uses common organic molecules with well-defined structures ( Chemical Formula 1) rather than complex coordination compounds of heavy metals, significantly reducing compound complexity and simplifying the overall device structure while achieving comparable luminous efficiency.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dopant achieves high external quantum efficiency and color purity, replacing conventional phosphorescent dopants containing heavy metals like iridium or platinum, while being cost-effective and efficient.

Implementation Method 1

reducing the energy gap between singlet and triplet states, allowing for reverse intersystem crossing

Methodology Applied
Scientific EffectReverse intersystem crossing:

Implementation Method 2

an organic light emitting diode is a device converting electrical energy into light by applying current to an organic light emitting material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12077699B2Dopant for organic optoelectronic device, organic optoelectronic device, and display device
Publication Date: 2024.09.03 SAMSUNG SDI CO LTD
  • US12077699B2 patent drawing
  • US12077699B2 patent drawing
  • US12077699B2 patent drawing

AI summary

The present invention relates to: a dopant for an organic optoelectronic device, represented by chemical formula 1; an organic optoelectronic device including the dopant; and a display device.