Organic Electroluminescent Device Dual Host Material Blue Light

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Solution Overview

Problem

Current blue phosphorescent organic electroluminescent devices face limitations in voltage, efficiency, and lifetime, particularly for blue light emission, and existing technologies have not effectively utilized dual host materials with metal complexes in these devices.

Innovation Solution

An organic electroluminescent device employing a new material combination featuring a first compound with a specific structure, a first host material, and a second host material with high triplet energy levels, where the triplet energy levels of both host materials are higher than that of the first compound, used in the light-emitting layer to enhance device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a single host material is used in the light-emitting layer, then the device structure is simple, but the device performance (voltage, efficiency, lifetime) is limited

Engineering Contradiction:
Improvedevice lifetimeVSAvoidhost material combination
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining two different host materials (first host material and second host material) in the light-emitting layer. The first host material has a triplet energy level of 2.69 eV or higher, while the second host material has a triplet energy level of 2.1 eV or higher. This composite host material system enables the device to achieve long lifetime and high efficiency while maintaining a practical structure, directly resolving the contradiction between device performance and structural simplicity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If phosphorescent emitters are used to achieve 100% IQE, then efficiency is improved, but blue phosphorescent devices still suffer from short lifetime and high operating voltage

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the energy level parameters of the host materials to resolve the contradiction. Specifically, the first host material is selected with a triplet energy level of 2.69 eV or higher, and the second host material with a triplet energy level of 2.1 eV or higher. These parameter selections enable the device to simultaneously achieve high efficiency (through triplet harvesting) and long lifetime by preventing triplet exciton accumulation that would otherwise degrade the blue phosphorescent emitter.

Inventive Principle:
Principle #35Parameter changes

3Power

If blue phosphorescent devices are designed for high efficiency, then operating voltage increases, but for low voltage operation efficiency decreases

Engineering Contradiction:
Improveoperating voltageVSAvoidemission efficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent introduces the second host material (with triplet energy level ≥2.1 eV) as an intermediary that facilitates efficient energy transfer to the blue phosphorescent emitter. This intermediary host material enables the device to maintain low operating voltage while achieving high emission efficiency, as it provides an optimal energy transfer pathway without requiring high voltage to drive the phosphorescent emission.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration results in improved overall device performance, including low voltage, high efficiency, and long lifetime, particularly for blue light emission, addressing the limitations of existing blue phosphorescent devices.

Implementation Method 1

a first host material having a high triplet energy level and a second host material having a high triplet energy level... The triplet energy levels of both host materials are higher than that of the first compound

Methodology Applied
Scientific EffectTriplet energy transfer: Phosphorescence

Implementation Method 2

organic electroluminescent device... comprises an anode, a cathode, and an organic layer disposed between the anode and the cathode, wherein the organic layer comprises a light-emitting layer

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240251654A1Organic electroluminescent device
Publication Date: 2024.07.25 BEIJING SUMMER SPROUT TECH CO LTD
  • US20240251654A1 patent drawing
  • US20240251654A1 patent drawing
  • US20240251654A1 patent drawing

AI summary

Provided is an organic electroluminescent device. The organic electroluminescent device includes an anode, a cathode and an organic layer disposed between the anode and the cathode, where the organic layer comprises at least a light-emitting layer, where the light-emitting layer comprises a first compound having a structure of Formula 1, a first host material having a high triplet energy level and a second host material having a high triplet energy level. The electroluminescent device exhibits excellent overall device performance, for example, a low voltage, high efficiency and a long lifetime. Further provided are an electronic device comprising the organic electroluminescent device and a compound composition comprising a first compound having a structure of Formula 1, a first host material having a high triplet energy level and a second host material having a high triplet energy level.