Organic EL Display Patterning via Soluble Release Layer

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Solution Overview

Problem

Conventional organic electroluminescence (EL) display devices using photolithography for patterning face challenges in achieving element characteristics comparable to those formed with metal masks, due to residual insulative layers and impurities, which deteriorate the organic EL element characteristics and limit pixel size and substrate size.

Innovation Solution

A method involving forming an organic compound layer, a release layer, processing the release layer into a desired shape, and removing the release layer using a polar solvent, where the lowermost layer of the release layer is soluble, allowing for precise patterning without the need for metal masks, thereby improving the element characteristics and enabling finer pixel sizes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If photolithography is used for patterning organic compound layers, then manufacturing complexity is reduced and productivity is improved, but residual insulative layers and impurities remain that deteriorate element characteristics

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidelement characteristics
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent extracts and removes the harmful residual insulative layer and impurities from the organic compound layer surface through selective etching processes. The etching solution specifically targets and removes the photolithography residues without damaging the underlying organic compound layer, thereby eliminating the source of element characteristic deterioration while maintaining the productivity benefits of photolithography.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical parameters of the etching solution to achieve selective removal of residues. By carefully controlling the composition, concentration, and treatment conditions of the etching solution, the process selectively removes insulative layer residues and impurities while preserving the organic compound layer integrity, thus improving element characteristics without sacrificing manufacturing efficiency.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If metal masks are used for vapor deposition patterning, then element characteristics are maintained, but manufacturing complexity increases and productivity decreases

Engineering Contradiction:
Improveelement characteristicsVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent replaces the mechanical metal mask system with a chemical etching system. Instead of using physical masks that require alignment, handling, and cleaning, the invention uses a chemically selective etching process that patterns the organic compound layer directly. This substitution eliminates the mechanical complexity of metal masks while maintaining pattern precision and improving manufacturing throughput.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent introduces an intermediary insulative layer that facilitates the patterning process. This intermediate layer is deposited over the organic compound layer, patterned using photolithography, and then used as a mask for selective etching. The intermediary layer enables precise patterning without requiring direct metal mask contact with the organic layer, thereby simplifying the manufacturing process while maintaining element characteristics.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If pixel size is reduced below 100 μm, then display resolution is improved, but mask fineness requirements increase manufacturing complexity

Engineering Contradiction:
Improvepixel sizeVSAvoidmask fineness
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the mechanical constraint of metal mask fineness with a chemical patterning approach. By using photolithography combined with selective etching, the process can achieve sub-100 μm pixel dimensions without requiring proportionally finer metal masks. The chemical etching process maintains pattern fidelity at reduced dimensions, enabling higher display resolution without increasing device complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent transitions from two-dimensional mask plane constraints to three-dimensional selective etching control. By depositing an intermediary insulative layer and using photolithographic patterning in the vertical dimension, the process achieves fine horizontal pixel dimensions without being constrained by mask fineness in the horizontal plane. This dimensional transition enables reduced pixel sizes while maintaining manufacturing simplicity.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

4Area of stationary object

If substrate size is increased for large format displays, then display area is improved, but mask stiffness requirements increase weight and handling difficulty

Engineering Contradiction:
Improvesubstrate sizeVSAvoidmask weight
Core Design Contradiction:
Area of stationary objectVSWeight of stationary object

Solution Approach 1:

The patent replaces the heavy mechanical metal mask system with a lightweight photolithographic patterning system. The intermediary insulative layer and photomask used in the new process are significantly lighter than large-format metal masks, reducing handling difficulty and equipment requirements. This substitution enables large substrate processing while minimizing the weight and complexity of the patterning tools.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses the vertical dimension of the intermediary insulative layer to achieve horizontal patterning without requiring large, stiff masks. The photolithographic process exposes the entire substrate area through optical projection, eliminating the need for mechanically stiff masks that would be required for direct contact patterning of large substrates. This approach enables large-format display manufacturing with reduced tooling weight and improved handling.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the production of organic EL display devices with element characteristics comparable to those formed with metal masks, while allowing for finer pixel sizes and larger substrate formats, enhancing the manufacturing process and reducing residual impurities and layer thickness variations.

Implementation Method 1

at least a lowermost layer of the release layer is a deposited film formed of a material soluble in a polar solvent

Methodology Applied
Scientific EffectSolubility: Solvation

Implementation Method 2

an organic compound layer in the element is a thin film layer formed by forming a thin film made of an organic material by vapor deposition or the like

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentUS9155160B2Method of manufacturing organic electroluminescence display device and electronic equipment including organic electroluminescence display device manufactured by the manufacturing method
Publication Date: 2015.10.06 CANON KK
  • US9155160B2 patent drawing
  • US9155160B2 patent drawing
  • US9155160B2 patent drawing

AI summary

Provided is a method of manufacturing an organic electroluminescence display device including an organic electroluminescence element, which has element characteristics comparable to those in the case of a vacuum in-situ process, while utilizing a patterning approach based on photolithography. The method of manufacturing an organic electroluminescence display device includes: an organic compound layer-forming step of forming an organic compound layer at least on a first electrode; a release layer-forming step of forming a release layer on the organic compound layer; a release layer-processing step of processing the release layer; and an organic compound layer-processing step of removing the organic compound layer in a region not covered with the release layer processed in the release layer-processing step, and at least the lowermost layer out of the release layer is a deposited film formed of a material soluble in a polar solvent.