Bilayer Organic Transparent Electrode for Low-Resistance Indoor OPV

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current photovoltaic modules with organic photovoltaic cells have low conversion efficiency under indoor radiation due to high series resistance, inadequate shunt resistances, and the use of indium tin oxide layers, which are costly and complex to deposit, leading to poor performance and high waste generation.

Innovation Solution

A photovoltaic module design featuring a bilayer lower electrode composed of a polymer blend and an organic polymer or molecule, eliminating the need for indium tin oxide, and manufactured using digital inkjet printing, with a process that reduces manufacturing costs and environmental impact.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If indium tin oxide layers are used as lower electrode, then transparency and charge collection are improved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvecharge collectionVSAvoiddeposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent removes the indium tin oxide layer from the device structure and replaces it with organic polymer layers. This extraction of the problematic material eliminates the complex deposition process while maintaining the electrode's functional requirements through alternative organic materials that can be applied using simpler techniques.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs organic polymer materials that are less expensive and easier to process than indium tin oxide. These organic materials can be deposited using inkjet printing or other low-cost methods, replacing the expensive and complex metal oxide deposition process with more economical alternatives.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Reliability

If indium tin oxide layers are used as lower electrode, then charge collection is improved, but manufacturing cost increases

Engineering Contradiction:
Improvecharge collectionVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent substitutes expensive indium tin oxide with cheaper organic polymer materials that maintain adequate charge collection functionality. This material replacement significantly reduces manufacturing costs while preserving the essential electrical performance required for charge collection.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the material parameters from inorganic metal oxides to organic polymers, altering the deposition method from complex physical vapor deposition or chemical deposition to simpler techniques like inkjet printing. This parameter change reduces both material cost and manufacturing complexity.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional electrode structure is used, then charge collection is improved, but series resistance increases under indoor radiation

Engineering Contradiction:
Improvecharge collectionVSAvoidseries resistance
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent employs composite organic polymer structures that combine multiple materials with complementary properties. These composite organic electrodes achieve optimal balance between transparency, conductivity, and charge collection efficiency, reducing series resistance under indoor lighting conditions while maintaining good charge collection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the electrical and optical parameters of the electrode layers by selecting specific organic polymer combinations and thicknesses. This parameter optimization reduces series resistance and improves charge collection efficiency under indoor radiation conditions.

Inventive Principle:
Principle #35Parameter changes

4Ease of manufacture

If inkjet printing technique is used, then manufacturing simplicity is improved, but manufacturing precision requirements increase

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidlayer thickness control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent optimizes the inkjet printing parameters including droplet size, deposition speed, and ink composition to achieve precise layer thickness control. By adjusting these parameters, the process maintains simplicity while achieving the required manufacturing precision for functional electrode layers.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs multiple deposition passes or overlapping patterns to achieve precise thickness control. Instead of relying on single-pass precision, the process uses partial overlaps and cumulative deposition to reach the target thickness, maintaining manufacturing simplicity while achieving precision through iterative application.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The bilayer electrode design enhances charge collection and reduces leakage currents, enabling efficient operation under indoor lighting conditions and reducing manufacturing complexity and waste.

Implementation Method 1

a first layer comprising a polymer blend of poly(3,4-ethylenedioxythiophene) and sodium poly(styrene sulfonate) covering the support... which serves here as anode... This indium tin oxide layer consists of a metal oxide which, in addition to conducting current, offers the property of being relatively transparent

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

an organic photovoltaic cell is a photovoltaic cell in which at least the active layer is made of an organic material... the possibility of substituting inorganic semiconductors generally used in photovoltaic cells... increases the number of systems that can be produced

Methodology Applied
Scientific EffectPhotovoltaic effect: Photovoltaic Effect

Implementation Method 3

the development of organic photovoltaic cells has evolved through the use of the inkjet printing technique for their implementation... in 2014, the Applicant developed a process for manufacturing photovoltaic cells using this technique for printing part of the layers of these cells

Methodology Applied
Scientific EffectInkjet printing:

Data Source

PatentUS20250380561A1Organic transparent conductive electrode for replacement of the ITO electrode in indoor-compatible organic photovoltaic modules
Publication Date: 2025.12.11 DRACULA TECH
  • US20250380561A1 patent drawing
  • US20250380561A1 patent drawing

AI summary

The present invention relates to a photovoltaic module comprising, amongst others, a lower electrode consisting of two layers: a first layer comprising a polymer blend of poly(3,4-ethylenedioxythiophene) and sodium poly(styrene-sulfonate) covering the support and having an average thickness between 50 nm and 150 nm and an organic fibrous structure, and a second layer based on an organic polymer or molecule covering said first layer, the lower electrode having a lower surface in contact with the support and an upper surface, and an upper electrode comprising a polymer blend of poly(3,4-ethylenedioxythiophene) and sodium poly(styrene-sulfonate) covering said photovoltaic active layer, said electrode being continuous, having an average thickness of between 100 nm and 400 nm and an organic fibrous structure.