Bilayer Organic Transparent Electrode for Low-Resistance Indoor OPV
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Solution Overview
Problem
Current photovoltaic modules with organic photovoltaic cells have low conversion efficiency under indoor radiation due to high series resistance, inadequate shunt resistances, and the use of indium tin oxide layers, which are costly and complex to deposit, leading to poor performance and high waste generation.
Innovation Solution
A photovoltaic module design featuring a bilayer lower electrode composed of a polymer blend and an organic polymer or molecule, eliminating the need for indium tin oxide, and manufactured using digital inkjet printing, with a process that reduces manufacturing costs and environmental impact.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If indium tin oxide layers are used as lower electrode, then transparency and charge collection are improved, but manufacturing complexity and cost increase
Solution Approach 1:
The patent removes the indium tin oxide layer from the device structure and replaces it with organic polymer layers. This extraction of the problematic material eliminates the complex deposition process while maintaining the electrode's functional requirements through alternative organic materials that can be applied using simpler techniques.
Solution Approach 2:
The patent employs organic polymer materials that are less expensive and easier to process than indium tin oxide. These organic materials can be deposited using inkjet printing or other low-cost methods, replacing the expensive and complex metal oxide deposition process with more economical alternatives.
2Reliability
If indium tin oxide layers are used as lower electrode, then charge collection is improved, but manufacturing cost increases
Solution Approach 1:
The patent substitutes expensive indium tin oxide with cheaper organic polymer materials that maintain adequate charge collection functionality. This material replacement significantly reduces manufacturing costs while preserving the essential electrical performance required for charge collection.
Solution Approach 2:
The patent changes the material parameters from inorganic metal oxides to organic polymers, altering the deposition method from complex physical vapor deposition or chemical deposition to simpler techniques like inkjet printing. This parameter change reduces both material cost and manufacturing complexity.
3Reliability
If conventional electrode structure is used, then charge collection is improved, but series resistance increases under indoor radiation
Solution Approach 1:
The patent employs composite organic polymer structures that combine multiple materials with complementary properties. These composite organic electrodes achieve optimal balance between transparency, conductivity, and charge collection efficiency, reducing series resistance under indoor lighting conditions while maintaining good charge collection.
Solution Approach 2:
The patent optimizes the electrical and optical parameters of the electrode layers by selecting specific organic polymer combinations and thicknesses. This parameter optimization reduces series resistance and improves charge collection efficiency under indoor radiation conditions.
4Ease of manufacture
If inkjet printing technique is used, then manufacturing simplicity is improved, but manufacturing precision requirements increase
Solution Approach 1:
The patent optimizes the inkjet printing parameters including droplet size, deposition speed, and ink composition to achieve precise layer thickness control. By adjusting these parameters, the process maintains simplicity while achieving the required manufacturing precision for functional electrode layers.
Solution Approach 2:
The patent employs multiple deposition passes or overlapping patterns to achieve precise thickness control. Instead of relying on single-pass precision, the process uses partial overlaps and cumulative deposition to reach the target thickness, maintaining manufacturing simplicity while achieving precision through iterative application.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The bilayer electrode design enhances charge collection and reduces leakage currents, enabling efficient operation under indoor lighting conditions and reducing manufacturing complexity and waste.
Implementation Method 1
a first layer comprising a polymer blend of poly(3,4-ethylenedioxythiophene) and sodium poly(styrene sulfonate) covering the support... which serves here as anode... This indium tin oxide layer consists of a metal oxide which, in addition to conducting current, offers the property of being relatively transparent
Implementation Method 2
an organic photovoltaic cell is a photovoltaic cell in which at least the active layer is made of an organic material... the possibility of substituting inorganic semiconductors generally used in photovoltaic cells... increases the number of systems that can be produced
Implementation Method 3
the development of organic photovoltaic cells has evolved through the use of the inkjet printing technique for their implementation... in 2014, the Applicant developed a process for manufacturing photovoltaic cells using this technique for printing part of the layers of these cells
Data Source
AI summary
The present invention relates to a photovoltaic module comprising, amongst others, a lower electrode consisting of two layers: a first layer comprising a polymer blend of poly(3,4-ethylenedioxythiophene) and sodium poly(styrene-sulfonate) covering the support and having an average thickness between 50 nm and 150 nm and an organic fibrous structure, and a second layer based on an organic polymer or molecule covering said first layer, the lower electrode having a lower surface in contact with the support and an upper surface, and an upper electrode comprising a polymer blend of poly(3,4-ethylenedioxythiophene) and sodium poly(styrene-sulfonate) covering said photovoltaic active layer, said electrode being continuous, having an average thickness of between 100 nm and 400 nm and an organic fibrous structure.

