Organic Electroluminescence Element Light Extraction

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Solution Overview

Problem

Organic electroluminescence elements suffer from low light extraction efficiency due to the non-directive nature of light emission from the light emission layer, resulting in insufficient light output and dark images, as only 15-20% of emitted light can be extracted due to total internal reflection and scattering, with existing methods like concavity on substrates or diffraction gratings being costly and prone to defects.

Innovation Solution

Employing a transparent resin film with hard coat layers on both sides, where the refractive indices of the hard coat layers are balanced to minimize reflections, and incorporating light scattering fillers to enhance light extraction efficiency while maintaining film properties like abrasion resistance and adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a transparent substrate with conventional structure is used, then the element structure is simple, but the light extraction efficiency is low (only 15-20% of light can be extracted)

Engineering Contradiction:
Improvestructure simplicityVSAvoidlight extraction efficiency
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The patent introduces a transparent resin film as an intermediary layer between the substrate and the light emission layer. This resin film has a refractive index (1.3-1.6) lower than both the substrate (1.5-1.7) and the light emission layer (1.7-2.1), acting as a mediator to reduce total internal reflection and improve light extraction efficiency to 30% or more while maintaining structural simplicity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the refractive index parameter of the substrate system by using a transparent resin film with specifically controlled refractive index (1.3-1.6). This parameter change creates optimal conditions for reducing total internal reflection at interfaces, thereby improving light extraction efficiency without complicating the overall structure

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If the refractive index of the light emission layer is high (1.7-2.1), then the light emission intensity is high, but the light extraction efficiency decreases due to total internal reflection

Engineering Contradiction:
Improvelight emission intensityVSAvoidlight extraction efficiency
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The transparent resin film serves as an intermediary layer with refractive index (1.3-1.6) lower than the light emission layer (1.7-2.1). This intermediary structure reduces the refractive index difference at the interface, minimizing total internal reflection and enabling more light to escape while preserving the high emission intensity characteristics of the light emission layer

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If a transparent resin film with hard coat layers is used to improve durability, then the abrasion resistance and adhesion are improved, but the refractive index matching becomes more complex

Engineering Contradiction:
ImprovedurabilityVSAvoidrefractive index matching complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the protective structure into distinct functional layers: a transparent resin film base layer and hard coat layers applied on its surfaces. This segmentation allows the base layer to provide optical functions (refractive index matching) while the hard coat layers provide mechanical protection, with each layer optimized for its specific function

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent creates a composite structure combining the transparent resin film with hard coat layers. The transparent resin film provides optimal refractive index (1.3-1.6) for light extraction, while the hard coat layers provide enhanced abrasion resistance and adhesion. The composite structure achieves both optical performance and mechanical durability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Significantly improves light extraction efficiency and film properties, allowing for higher luminance with reduced power consumption and improved durability of the organic electroluminescence element.

Implementation Method 1

each refractive index of the hard coat layers satisfies Expressions (1)-(4)... the transparent substrate has a function to scatter aa light to the light emission side

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 2

only 15 to 20% of the light emitted in the light emission layer can be extracted. This is because light which enters a boundary (a boundary between a transparent substrate and the atmosphere) at an angle θ larger than a critical angle is totally reflected

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Implementation Method 3

the transparent substrate has a function to scatter aa light to the light emission side with respect to the organic electroluminescence layer

Methodology Applied
Scientific EffectScattering: Scattering

Implementation Method 4

an electron and a hole were injected into the light emission layer and recombined to form an exciton. The element emits light, utilizing light (fluorescent light or phosphorescent light) generated by inactivation of the exciton

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS8686630B2Organic electroluminescence element and illumination device using the same
Publication Date: 2014.04.01 MERCK PATENT GMBH
  • US8686630B2 patent drawing

AI summary

Disclosed are an organic electroluminescence element with significantly improved light extraction efficiency and improved film properties and an illumination device that uses said element. The organic electroluminescence element has a transparent electrode, an organic electroluminescence layer, and a cathode sequentially stacked on a transparent base material. The element is characterized in that the transparent base material is a transparent resin film, there is a hard coat layer on both sides, the respective refractive indices satisfy the expressions (1)-(4), and there is a function to scatter light to the light emission side with respect to the organic electroluminescence layer. Expression (1): −0.2≦n(H1)−n(A)≦0.2, Expression (2): −0.1≦n(H1)−n(B)≦0.1, Expression (3): −0.1≦n(H2)−n(B)≦0.1, Expression (4): −0.1≦n(H1)−n(H2)≦0.1. In the expressions, n(A) is the refractive index of the transparent electrode; n(H1) is the refractive index of the hard coat layer (on the transparent electrode side); n(H2) is the refractive index of the hard coat layer (on the side opposite the transparent electrode); and n(B) is the refractive index of the transparent resin film.