Organic Electroluminescent Compounds for Low Voltage OLEDs

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Solution Overview

Problem

Current organic electroluminescent devices face challenges in achieving low driving voltage, high current and power efficiencies, and extended operational lifespan, particularly due to issues with light-emitting materials and electron transport materials that can migrate and reduce color purity.

Innovation Solution

An organic electroluminescent compound with a rigid aromatic network, represented by a specific formula, is used as a host, electron buffer, or electron transport material, facilitating fast electron current properties through intermolecular stacking and interaction, thereby enhancing device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If conventional electron transport materials (e.g., Alq3) are used, then excellent electron transfer capability is achieved, but the materials migrate to other layers and lower color purity

Engineering Contradiction:
Improveelectron transfer speedVSAvoidcolor purity
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The patent modifies the molecular structure of electron transport materials by introducing specific substituents (e.g., fluorine atoms, bulky aryl groups) to change physical and chemical parameters such as molecular weight, steric hindrance, and electron affinity. These parameter changes prevent material migration while maintaining fast electron transfer, thus resolving the contradiction between electron transfer speed and color purity stability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite electron transport materials that combine multiple functional groups within a single molecular structure. These composite molecules integrate high electron mobility characteristics with structural features that prevent migration, achieving both fast electron transfer and stable color purity simultaneously.

Inventive Principle:
Principle #40Composite materials

2Temperature

If host materials with high molecular weight are used, then thermal stability is improved, but vacuum deposition becomes difficult

Engineering Contradiction:
Improvethermal stabilityVSAvoidvacuum deposition
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent optimizes the molecular weight parameter of host materials to a specific range that balances thermal stability and vapor pressure. By carefully controlling molecular weight and introducing appropriate functional groups, the materials achieve sufficient thermal stability while maintaining vapor pressure adequate for vacuum deposition processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces localized functional groups with specific properties (e.g., fluorine substitution, aromatic rings) into the host material structure. These local modifications enhance thermal stability at critical positions without significantly increasing overall molecular weight, thus preserving vacuum deposition capability while improving thermal performance.

Inventive Principle:
Principle #3Local quality

3Duration of action of stationary object

If electron buffer layer is added to improve luminance stability at high temperature, then device lifespan is extended, but device complexity increases

Engineering Contradiction:
Improvedevice lifespanVSAvoidlayer structure
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent develops electron transport materials that simultaneously perform multiple functions: electron transport, electron buffering, and thermal stabilization. This multi-functionality eliminates the need for separate electron buffer layers, extending device lifespan without increasing structural complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the functions of the electron buffer layer and electron transport layer into a single integrated layer using compounds with dual functionality. This consolidation reduces the number of layers while maintaining the protective effect against high-temperature degradation and extending device operational life.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound achieves low driving voltage and high luminous efficiency while extending the lifespan of organic electroluminescent devices by stabilizing the molecular framework and improving electron transport.

Implementation Method 1

By this energy, organic luminescent compounds reach an excited state, and light emission occurs by emitting light from energy due to returning from the excited state of the organic luminescent compounds to a ground state

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

facilitating fast electron current properties through intermolecular stacking and interaction

Methodology Applied
Scientific EffectIntermolecular stacking and interaction: Van der Waals Force

Data Source

PatentUS11527728B2Organic electroluminescent compounds and organic electroluminescent device comprising the same
Publication Date: 2022.12.13 DUPONT SPECIALTY MATERIALS KOREA LTD
  • US11527728B2 patent drawing
  • US11527728B2 patent drawing
  • US11527728B2 patent drawing

AI summary

The present disclosure relates to organic electroluminescent compounds, and a host material, an electron buffer material, an electron transport material and an organic electroluminescent device comprising the same. By using the organic electroluminescent compounds of the present disclosure, the organic electroluminescent device secures fast electron current properties by intermolecular stacking and interaction, and thus, it is possible to provide the organic electroluminescent device having low driving voltage and/or excellent luminous efficiency and/or efficient lifespan properties.