Organic Electron-Transport Material for OLED Efficiency

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Solution Overview

Problem

Current light-emitting devices, particularly organic electroluminescence (EL) devices, face challenges in achieving high emission efficiency, long lifetime, low driving voltage, and low power consumption while maintaining reliability.

Innovation Solution

A light-emitting device structure incorporating an anode, a cathode, and an electroluminescent (EL) layer with a light-emitting layer and an electron-transport layer, where the electron-transport layer contains an organic compound with specific skeletons for electron and hole transport, and a monocyclic π-electron deficient heteroaromatic ring, optimized for efficient energy transport and reduced driving voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional electron-transport materials are used in organic EL devices, then device structure can be maintained, but emission efficiency is insufficient and lifetime is short

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the electron-transport material by introducing a specific molecular architecture comprising a first skeleton (electron-transporting), a second skeleton (hole-accepting with condensed aromatic hydrocarbon), and a third skeleton (monocyclic π-electron deficient heteroaromatic ring). This structural parameter change enables simultaneous improvement in emission efficiency and device lifetime by optimizing electron and hole transport properties at the molecular level.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite electron-transport material that integrates three distinct functional skeletons into a single molecule. The first skeleton provides electron transport capability, the second skeleton (condensed aromatic hydrocarbon) provides hole acceptance, and the third skeleton provides additional electron transport and structural stability. This composite molecular structure resolves the contradiction by combining multiple functions that individually address different aspects of device performance.

Inventive Principle:
Principle #40Composite materials

2Use of energy by stationary object

If traditional light-emitting device structures are used, then manufacturing simplicity is maintained, but power consumption remains high

Engineering Contradiction:
Improvepower consumptionVSAvoidstructural complexity
Core Design Contradiction:
Use of energy by stationary objectVSEase of manufacture

Solution Approach 1:

The patent designs an electron-transport material that performs multiple functions simultaneously: electron transport (first skeleton), hole acceptance (second skeleton), and enhanced emission efficiency (third skeleton). This multi-functionality reduces the need for additional separate layers or components, thereby lowering power consumption without significantly increasing manufacturing complexity. The single material accomplishes what would traditionally require multiple functional components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If existing electron-transport materials are used, then device operation is maintained, but initial decay is high and reliability is reduced

Engineering Contradiction:
Improveinitial decay resistanceVSAvoidemission efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies local quality by assigning specific functional characteristics to different parts (skeletons) of the electron-transport material molecule. The first skeleton is optimized for electron transport, the second skeleton (condensed aromatic hydrocarbon) is optimized for hole acceptance and stability, and the third skeleton is optimized for electron transport and reducing decay. This localized functional optimization within the molecular structure enables the material to simultaneously achieve high emission efficiency and resistance to initial decay.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed structure enhances emission efficiency, extends device lifetime, reduces power consumption, and improves reliability by optimizing energy transport and reducing initial decay, thus addressing the limitations of existing light-emitting devices.

Implementation Method 1

The electron-transport layer contains an electron-transport material. The electron-transport material is an organic compound including a first skeleton, a second skeleton, and a third skeleton. The first skeleton has a function of transporting an electron.

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

The second skeleton has a function of accepting a hole.

Methodology Applied
Scientific EffectHole transport: Conduction (electrical)

Implementation Method 3

Carriers are injected by application of voltage to the device, and recombination energy of the carriers is used, whereby light emission can be obtained from the light-emitting material.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20210028371A1Light-emitting device, light-emitting apparatus, electronic device, lighting device, and compound
Publication Date: 2021.01.28 SEMICON ENERGY LAB CO LTD
  • US20210028371A1 patent drawing
  • US20210028371A1 patent drawing
  • US20210028371A1 patent drawing

AI summary

A novel light-emitting device is provided. A light-emitting device with high emission efficiency is provided. A light-emitting device having a long lifetime is provided. A light-emitting device with low driving voltage is provided. The light-emitting device includes an anode, a cathode, and an EL layer between the anode and the cathode. The EL layer includes a light-emitting layer and an electron-transport layer. The electron-transport layer is positioned between the light-emitting layer and the cathode. The electron-transport layer contains an electron-transport material. The electron-transport material is an organic compound including a first skeleton, a second skeleton, and a third skeleton. The first skeleton has a function of transporting electrons. The second skeleton has a function of accepting holes. The third skeleton includes a monocyclic π-electron deficient heteroaromatic ring.