Organic Electronic Element Compound for Charge Balance

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Solution Overview

Problem

Current organic electric elements face challenges in achieving high luminous efficiency, low driving voltage, and extended lifespan due to charge imbalance and material limitations in the hole transport layer and emission-auxiliary layer, which affect color purity and efficiency.

Innovation Solution

The development of organic electric elements using a compound with a specific molecular structure, represented by Formula 1, that optimizes energy levels and T1 values, enhancing mobility and interfacial properties across layers to improve charge balance and reduce driving voltage, thereby improving efficiency and lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a material with low HOMO value is used in the hole transport layer, then hole transport capability is improved, but T1 value becomes low causing exciton transport to the hole transport layer, resulting in charge unbalance and reduced color purity

Engineering Contradiction:
Improvehole mobilityVSAvoidcharge balance
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent introduces an emission-auxiliary layer as an intermediary between the hole transport layer and the light emitting layer. This intermediate layer has high T1 energy value and wide band gap, which prevents exciton transport to the hole transport layer while maintaining hole transport capability, thus resolving the charge unbalance issue

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the energy level parameters (HOMO, LUMO, T1 value, band gap) of the materials used in different layers. Specifically, the emission-auxiliary layer is designed with high T1 energy value and wide band gap to prevent exciton leakage, while the hole transport layer maintains low HOMO value for efficient hole transport

Inventive Principle:
Principle #35Parameter changes

2Power

If a material with rapid hole mobility is used to reduce driving voltage, then driving voltage is lowered, but efficiency decreases due to charge unbalance in the light emitting layer

Engineering Contradiction:
Improvedriving voltageVSAvoidluminous efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The emission-auxiliary layer acts as a mediator that allows rapid hole transport while preventing exciton loss to the hole transport layer. This enables the use of materials with rapid hole mobility without sacrificing luminous efficiency

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the energy level parameters of the emission-auxiliary layer (high T1 energy value, wide band gap) to create an energy barrier that prevents exciton transport to the hole transport layer, thereby maintaining charge balance and efficiency while allowing rapid hole transport

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If the organic material layer structure is simplified, then device complexity is reduced, but it becomes difficult to achieve optimal combination of energy levels and T1 values for high efficiency and long lifespan

Engineering Contradiction:
Improveorganic material layer structureVSAvoidefficiency and lifespan
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent segments the organic material layer into multiple functional layers (hole injection layer, hole transport layer, emission-auxiliary layer, light emitting layer, electron transport layer, electron injection layer). Each layer is optimized for its specific function, allowing independent optimization of energy levels and T1 values without increasing overall device complexity

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the compound results in organic electric elements with enhanced luminous efficiency, reduced driving voltage, and improved color purity and lifespan, addressing the limitations of existing materials by optimizing energy levels and interfacial properties.

Implementation Method 1

a hole transferred from a hole transport layer to the light emitting layer are recombined to form an exciton

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Implementation Method 2

an optimal combination of energy levels and T1 values, inherent material properties (mobility, interfacial properties, etc.)

Methodology Applied
Scientific EffectEnergy level alignment:

Implementation Method 3

an electron transferred from an electron transport layer to a light emitting layer and a hole transferred from a hole transport layer to the light emitting layer are recombined to form an exciton

Methodology Applied
Scientific EffectExciton formation:

Implementation Method 4

having high T1 energy value and wide band gap

Methodology Applied
Scientific EffectEnergy barrier:

Implementation Method 5

An organic light emitting phenomenon refers to a phenomenon in which electric energy is converted into light energy of an organic material

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 6

enhancing mobility and interfacial properties across layers to improve charge balance

Methodology Applied
Scientific EffectInterfacial charge transfer: Conduction (electrical)

Data Source

PatentUS10658597B2Organic electronic element comprising compound for organic electronic element, and electronic device thereof
Publication Date: 2020.05.19 DUK SAN NEOLUX
  • US10658597B2 patent drawing
  • US10658597B2 patent drawing
  • US10658597B2 patent drawing

AI summary

An organic electric element includes a first electrode, a second electrode, and an organic material layer between the first electrode and the second electrode. The organic material layer includes the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, stability, and life span can be improved.