Organic Compound for Green Light Sensing in Image Sensors

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Solution Overview

Problem

Conventional silicon photodiodes used in image sensors have limited sensitivity due to smaller absorption areas, necessitating the development of organic materials that can replace silicon and improve sensitivity by selectively absorbing light in specific wavelength regions.

Innovation Solution

A compound represented by Chemical Formula 1, which includes a substituted or unsubstituted 5- or 6-membered aromatic ring, is used in an organic photoelectric device, allowing it to sense light in the green wavelength region with improved thermal stability and efficiency, and is integrated into an image sensor and electronic device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If silicon photodiode size is reduced to achieve higher resolution, then pixel density improves, but sensitivity deteriorates due to smaller absorption area

Engineering Contradiction:
ImproveresolutionVSAvoidsensitivity
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent changes the material parameter from silicon to organic compound, which fundamentally alters the absorption characteristics. The organic compound enables selective wavelength absorption with higher extinction coefficients, allowing small pixels to maintain high sensitivity by optimizing the absorption parameter rather than increasing physical size

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite molecular structures combining electron-donating groups and electron-accepting groups in specific arrangements. This composite approach creates materials with tailored optical properties, achieving both small size compatibility and high sensitivity through optimized molecular composition rather than bulk material properties

Inventive Principle:
Principle #40Composite materials

2Reliability

If organic material is used to replace silicon, then sensitivity and integration improve, but thermal stability becomes a concern

Engineering Contradiction:
ImprovesensitivityVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent optimizes molecular parameters including HOMO-LUMO energy gaps, thermal decomposition temperatures, and glass transition temperatures. By carefully selecting and tuning these parameters through molecular design, the organic compound achieves both high sensitivity and adequate thermal stability for device operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific functional groups and molecular moieties at localized positions within the organic compound structure. These local structural modifications enhance specific properties such as thermal stability and charge transport while maintaining the overall high sensitivity characteristics of the organic material

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compound enhances the sensitivity and efficiency of the organic photoelectric device by selectively absorbing light in the green wavelength region, improving the integration and performance of image sensors and electronic devices.

Implementation Method 1

A photoelectric device converts light into an electrical signal using photoelectric effects

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Implementation Method 2

The organic material has a relatively high extinction coefficient and selectively absorbs/sense light in a particular wavelength region depending on a molecular structure

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Data Source

PatentEP3026722B1Compound for organic photoelectric device and organic photoelectric device, image sensor, and electronic device including the same
Publication Date: 2021.01.06 SAMSUNG ELECTRONICS CO LTD
  • EP3026722B1 patent drawingFigure 8
  • EP3026722B1 patent drawingFigure 9
  • EP3026722B1 patent drawingFigure 10

AI summary

A compound for an organic photoelectric device is represented by Chemical Formula 1, and an organic photoelectric device, an image sensor and an electronic device include the same.