Organic Layer Metal Oxide Nanoparticles OLED Power Efficiency

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Solution Overview

Problem

Existing organic electronic devices, particularly organic light-emitting diodes (OLEDs), face challenges in reducing power consumption and extending operational lifetime while maintaining thermal stability and efficiency.

Innovation Solution

An organic electronic device comprising a first electrode, a second electrode, and a first organic layer with a composition of at least one metal organic compound and at least one metal oxide, specifically using rhenium oxide (ReO3) and carbene complexes, which optimizes the balance of materials to achieve low operating voltage, high efficiency, and prolonged lifetime.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If conventional organic materials are used in OLEDs, then the device structure is simpler, but power consumption is high and operational lifetime is short

Engineering Contradiction:
Improvepower consumptionVSAvoidlayer composition complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining organic compounds (hole transport material and emitter) with inorganic metal oxide nanoparticles (MoO3, V2O5, RuO2, or ReO3) to form a hybrid layer. This composite approach enables simultaneous achievement of low power consumption and long lifetime by leveraging the complementary properties of both organic and inorganic materials, while the nanoparticles serve multiple functions including charge transport enhancement and stability improvement without requiring fundamentally new device architectures

Inventive Principle:
Principle #40Composite materials

2Reliability

If metal oxide concentration is increased to reduce resistance, then electrical conductivity improves, but beyond 80 wt% the resistance increases again

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmetal oxide concentration
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent optimizes the metal oxide concentration parameter within the specific range of 20-80 wt%, identifying that the optimal conductivity is achieved at 40-60 wt%. This parameter optimization prevents the resistance increase that occurs at concentrations above 80 wt%, while still achieving the desired low-resistance state. The specific concentration range was determined through systematic experimentation to balance conductivity enhancement with material composition stability

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If phosphorescence emitters are used to increase quantum efficiency, then energy efficiency improves up to 4 times, but device complexity and material selection requirements increase

Engineering Contradiction:
Improveenergy efficiencyVSAvoidmaterial composition requirements
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent introduces metal oxide nanoparticles as intermediary materials that facilitate energy transfer and enhance the performance of phosphorescence emitters. These nanoparticles act as mediators between the electrical current and the phosphorescent materials, improving charge injection and transport efficiency. This intermediary approach enables achieving high energy efficiency (up to 4 times improvement) while simplifying the overall material selection process, as the nanoparticles provide a platform that enhances emitter performance without requiring complex device restructuring

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device exhibits superior power efficiency, quantum efficiency, and extended operational lifetime with reduced operating voltage, demonstrating improved performance over prior art by utilizing ReO3 and carbene complexes in the organic layer.

Implementation Method 1

the matrix material and the dopant form a charge transfer complex

Methodology Applied
Scientific EffectCharge transfer complex formation:

Implementation Method 2

OLEDs exploit the property of materials of emitting light when they are excited by electrical current

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

The phosphorescence emitters are typically organometallic complexes which, in contrast to the fluorescence emitters which exhibit singlet emission, exhibit triplet emission

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentUS9142792B2Organic electronic devices comprising a layer comprising at least one metal organic compound and at least one metal oxide
Publication Date: 2015.09.22 UDC IRELAND
  • US9142792B2 patent drawing
  • US9142792B2 patent drawing
  • US9142792B2 patent drawing

AI summary

The present invention relates to an organic electronic device including a first electrode, a second electrode and a first organic layer interposed between the first electrode and the second electrode, wherein the first organic layer comprises at least one metal organic compound and at least one metal oxide. The present invention further relates to an apparatus comprising the organic electronic device according to the present invention.