Organic Memory Element With Oxide Trapping Layer

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Solution Overview

Problem

Existing organic memory elements suffer from low cycle stability and high production costs, with unclear functional mechanisms and limited reproducibility.

Innovation Solution

An organic memory element design featuring an electrode, a counter-electrode, an oxide layer adjacent to the electrode, an electrically undoped organic layer, and an electrically doped organic layer, where the oxide layer facilitates charge carrier trapping and the doped layer ensures efficient charge injection, achieving hysteresis and improved ON/OFF current ratios.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic memory element designs are used, then the structure is simpler, but cycle stability is low and reproducibility is limited

Engineering Contradiction:
Improvecycle stabilityVSAvoidlayer structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The organic memory element is segmented into distinct functional layers: an electrically undoped organic layer and an electrically doped organic layer. This segmentation allows each layer to perform its specific function optimally, with the undoped layer providing stable charge storage and the doped layer enabling efficient charge injection, thereby improving cycle stability and reproducibility

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the organic memory element are assigned different electrical properties. The undoped organic layer region maintains electrical neutrality for stable charge storage, while the doped organic layer region is intentionally doped to facilitate charge injection. This local differentiation of electrical properties resolves the contradiction by optimizing each region's function

Inventive Principle:
Principle #3Local quality

2Reliability

If conventional organic memory element designs are used, then production costs may be lower, but cycle stability is poor

Engineering Contradiction:
Improvecycle stabilityVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The electrical doping parameter is changed in specific regions of the organic layer. By controlling the doping level and distribution, the memory element achieves superior cycle stability. The doping process can be implemented through standard semiconductor fabrication techniques, maintaining ease of manufacture while dramatically improving reliability

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the oxide layer is added for charge trapping, then data storage capability is improved, but device complexity increases

Engineering Contradiction:
Improvedata storage capabilityVSAvoidnumber of layers
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The oxide layer serves multiple functions simultaneously: it acts as a charge trapping layer for data storage, provides electrical insulation between layers, and facilitates interfacial charge transfer. This multi-functionality allows the oxide layer to improve data storage capability without proportionally increasing device complexity, as a single layer performs multiple critical roles

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances cycle stability and reduces production costs by achieving a high ON/OFF current ratio and extended data storage times, with the oxide layer's nanoporosity and doped organic layers ensuring effective charge storage and injection, respectively.

Implementation Method 1

The oxide layer is responsible in conjunction with the undoped organic layer for the emergence of hysteresis. It is believed that the function of the oxide layer is to store charge carriers in trapping states.

Methodology Applied
Scientific EffectCharge carrier trapping:

Implementation Method 2

By means of the doped layer, charge carriers can be effectively injected into the undoped organic layer.

Methodology Applied
Scientific EffectCharge carrier injection:

Data Source

PatentUS9006712B2Organic memory element
Publication Date: 2015.04.14 NOVALED GMBH
  • US9006712B2 patent drawing
  • US9006712B2 patent drawing
  • US9006712B2 patent drawing

AI summary

The invention relates to an organic memory with an electrode and a counter-electrode, comprising at least one oxide layer, an electrically undoped organic layer and an electrically doped organic layer between the electrode and the counter-electrode, wherein the oxide layer is adjacent to the electrode and the undoped organic layer.