Organic Photoelectric Compound for Stable OLED Efficiency

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Solution Overview

Problem

Current organic photoelectric devices face challenges in achieving excellent lifespan, efficiency, electrochemical stability, and thermal stability, particularly in materials used for organic light emitting diodes and other organic photoelectric devices, where interactions between molecules lead to reduced efficiency and color purity.

Innovation Solution

Development of compounds for organic photoelectric devices that serve as electron injection and transport materials, as well as light emitting hosts with appropriate dopants, specifically represented by Chemical Formulas 1 to 5, which include aryl and heteroaryl groups, pyrimidine, and triazine structures, enhancing stability and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If a host/dopant system is used as a light emitting material, then color purity and luminous efficiency are improved, but device complexity increases due to multiple material layers

Engineering Contradiction:
Improvecolor purityVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent combines the host material and dopant material into a single emission layer system, where the host material (compound of formula 1 or 2) and dopant material work synergistically to achieve both high color purity and luminous efficiency without requiring additional complex layers

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The host material serves multiple functions simultaneously: it acts as the matrix for energy transfer, provides structural stability, enables color purity through controlled energy levels, and facilitates dopant distribution, thereby reducing the need for separate functional layers

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If multiple material layers are used in the organic material layer, then efficiency and stability of the organic light emitting diode are improved, but manufacturing complexity increases

Engineering Contradiction:
ImprovestabilityVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent integrates hole transport, electron transport, and emission functions into a unified multi-layer structure where each layer has optimized thickness and material composition, balancing stability requirements with manufacturing feasibility through systematic material selection

Inventive Principle:
Principle #5Merging (Combining)

3Use of energy by moving object

If phosphorescent light emitting material is used, then luminous efficiency is improved through triplet exciton utilization, but electrochemical stability may be compromised

Engineering Contradiction:
Improveluminous efficiencyVSAvoidelectrochemical stability
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The patent modifies the chemical structure of the host material (using specific aryl and heteroaryl groups in formulas 1 and 2) to optimize the energy level alignment and electrochemical stability while maintaining efficient triplet exciton utilization for high luminous efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite emission layer system combining the specially designed host material with phosphorescent dopant, where the host material's stable molecular structure protects the phosphorescent dopant from degradation while enabling efficient energy transfer

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compounds provide organic photoelectric devices with improved electrochemical and thermal stability, extended lifespan, and high luminous efficiency at low driving voltage, suitable for various organic devices including OLEDs, solar cells, and transistors.

Implementation Method 1

the compound for an organic photoelectric device may act as an electron injecting and/or transporting material

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

the generated excitons generate light having certain wavelengths while shifting to a ground state

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 3

non-radiance transiting of a singlet exciton to a triplet exciton through intersystem crossing

Methodology Applied
Scientific EffectIntersystem crossing:

Implementation Method 4

excellent life-span, efficiency, electrochemical stability, and thermal stability

Methodology Applied
Scientific EffectThermal stability: Thermal Insulation

Implementation Method 5

excellent life-span, efficiency, electrochemical stability, and thermal stability

Methodology Applied
Scientific EffectElectrochemical stability:

Data Source

PatentEP3460024B1Compound for an organic photoelectric device, and organic photoelectric device comprising same
Publication Date: 2021.04.28 CHEIL INDUSTRIES INC
  • EP3460024B1 patent drawingFigure 1
  • EP3460024B1 patent drawingFigure 2
  • EP3460024B1 patent drawingFigure 3

AI summary

A compound for an organic photoelectric device and an organic photoelectric device including the same are disclosed, and the compound for an organic photoelectric device is represented by Chemical Formula 1. In Chemical Formula 1, Ar1 to Ar4 and R1 to R4 are the same as defined in the specification. The compound for an organic photoelectric device may provide an organic photoelectric device having excellent thermal/electrochemical stability and life-span, and efficiency.