Organic Photon Energy Up-conversion Composition

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Solution Overview

Problem

Existing photon energy up-conversion systems, both inorganic and organic, are limited by high manufacturing costs, unsuitability for large-area film formation, and inefficiency at low light intensities and ambient temperatures, with most organic systems requiring high temperatures and having limited versatility in wavelength applications.

Innovation Solution

A composition comprising two organic components, where one acts as a sensitizer and the other as an emitter, capable of absorbing and emitting energy at specific wavelength regions, enabling efficient photon energy up-conversion even at low pump intensities and ambient temperatures, suitable for large-area film formation and versatile applications.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If inorganic systems with sensitising and activator components are used for up-conversion, then up-conversion efficiency is improved, but manufacturing cost increases and suitability for large-area film formation decreases

Engineering Contradiction:
Improveup-conversion efficiencyVSAvoidmanufacturing cost and film formation suitability
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive inorganic sensitising and activator components with organic compounds that perform the same up-conversion function. The organic compounds are cheaper to manufacture and process, enabling cost-effective production while maintaining up-conversion efficiency. The organic nature allows for solution processing and large-area film formation techniques.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the material phase from inorganic solid-state systems to organic molecular systems. This parameter change enables the use of solution processing methods, spin-coating, and other techniques suitable for large-area film formation on flexible substrates, while preserving the energy transfer mechanism through molecular design.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If organic compounds are used for up-conversion, then manufacturing cost decreases and film formation capability improves, but up-conversion efficiency at low light intensities and ambient temperatures worsens

Engineering Contradiction:
Improvemanufacturing cost and film formation capabilityVSAvoidup-conversion efficiency at low light intensities and ambient temperatures
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent employs an energy transfer mechanism where the organic sensitiser acts as an intermediary that absorbs low-energy photons and transfers energy to the emitter. This two-step process enables efficient up-conversion at low light intensities by utilizing the high absorption cross-section of the sensitiser and the efficient energy transfer to the emitter, which then emits at higher energy wavelengths.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite organic system combining sensitiser and emitter compounds in a single material system. This composite approach allows optimization of both light absorption (via sensitiser) and light emission (via emitter), achieving high up-conversion efficiency at ambient conditions through synergistic molecular design and energy transfer coupling.

Inventive Principle:
Principle #40Composite materials

3Reliability

If inorganic crystalline systems are used, then up-conversion process is well-established, but versatility in wavelength applications and adaptability to different substrates decreases

Engineering Contradiction:
Improveup-conversion process stabilityVSAvoidwavelength application versatility and substrate adaptability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent designs organic compounds with tunable molecular structures that can be adjusted to absorb and emit at various wavelengths. The organic sensitiser-emitter system can be customized for different wavelength regions (UV, visible, NIR) and is compatible with multiple substrate types including flexible polymers, glass, and metals, providing universal applicability across different opto-electronic devices.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves efficient photon energy up-conversion across a range of wavelengths, enabling the development of versatile opto-electronic devices that can operate effectively at room temperature and low light intensities, with improved performance in large-area film formation.

Implementation Method 1

upon absorption of energy by the first component at the first wavelength region λ1, the emissive component emits energy at the second wavelength region λ2

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 2

a first component is capable of absorbing energy at a first wavelength region w≦λ1≦x

Methodology Applied
Scientific EffectAbsorption: Absorption (EM radiation)

Data Source

PatentUS7683363B2Composition for photon-energy up-conversion
Publication Date: 2010.03.23 SONY DEUT GMBH
  • US7683363B2 patent drawing
  • US7683363B2 patent drawing
  • US7683363B2 patent drawing

AI summary

The present invention relates to a composition for photon energy up-conversion, a system comprising said composition and to uses of said composition and said system.