Organic Probe Molecular Detection for Cyanide

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Solution Overview

Problem

Current methods for detecting gas components at extremely low concentrations, such as those found in disaster or terrorism sites, are limited by the need for large, expensive equipment and lack accuracy, particularly for detecting cyanide gases which are highly toxic and require sensitive and portable detection solutions.

Innovation Solution

A molecular detection apparatus using a collection unit, a detector with a sensor unit and organic probes featuring a dicyanovinyl or coumarin structure, and a discriminator to process detection signals, enabling selective and sensitive detection of gas components at ppt to ppb levels, including cyanide, through pattern recognition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If large equipment such as gas chromatography or mass spectrometer is used to detect gas components at extremely low concentrations, then detection sensitivity is improved, but device weight and volume increase

Engineering Contradiction:
Improvedetection sensitivityVSAvoiddevice weight
Core Design Contradiction:
Measurement precisionVSWeight of moving object

Solution Approach 1:

The patent divides the detection system into modular components: a compact sensor unit with organic probe-coated conductive layers, a portable gas chromatograph for sample introduction, and a mass spectrometer for analysis. This segmentation allows the use of high-sensitivity detection techniques while reducing overall device size and weight compared to traditional large-scale instrumentation.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent applies local quality enhancement by coating specific regions of conductive layers with organic probes that have high affinity for target gas molecules. This localized functionalization creates highly sensitive detection zones within the sensor, enabling extreme low-concentration detection without requiring the entire device to be large-scale equipment.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If large equipment such as gas chromatography or mass spectrometer is used to detect gas components at extremely low concentrations, then detection sensitivity is improved, but device cost increases

Engineering Contradiction:
Improvedetection sensitivityVSAvoiddevice cost
Core Design Contradiction:
Measurement precisionVSEase of manufacture

Solution Approach 1:

The patent employs disposable or replaceable organic probe coatings on conductive layers. These probes can be synthesized relatively cheaply and replaced when depleted or contaminated, avoiding the need for expensive, complex, and maintenance-intensive large-scale equipment while maintaining high detection sensitivity for extreme low-concentration gases.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Adaptability or versatility

If animal-based methods are used to detect explosive components, then detection capability is improved, but cost and accuracy consistency deteriorate

Engineering Contradiction:
Improvedetection capabilityVSAvoidaccuracy consistency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent replaces the biological detection system (trained police dogs) with a chemical sensing system based on organic probes coated on conductive layers. This substitution provides consistent, reproducible, and reliable detection results while maintaining the ability to detect explosive components at extremely low concentrations, eliminating the variability and ethical concerns associated with animal-based methods.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Ease of manufacture

If conventional organic substances are used as detection probes, then ease of manufacture is improved, but detection sensitivity for cyanide gases deteriorates

Engineering Contradiction:
Improveprobe availabilityVSAvoiddetection sensitivity
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The patent changes the chemical parameters of the organic probes by selecting specific substances with high affinity for cyanide gases, such as certain metal complexes or functionalized organic compounds. This parameter optimization enables highly sensitive detection of cyanide at extremely low concentrations while maintaining practical manufacturability, overcoming the limitations of conventional organic substances that lack sufficient cyanide-specific interaction.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The apparatus achieves highly sensitive and accurate detection of gas components at extremely low concentrations, improving portability and detection accuracy, and enabling real-time monitoring of hazardous gases like cyanide without relying on costly animal-based methods.

Implementation Method 1

an element has been known which has a conductive layer in which a surface of a carbon nanostructure or graphene is surface modified with an organic substance or the like that selectively reacts with or adsorbs a specific substance

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

measures a potential difference or the like that changes depending on the gas component having adhered to the surface of a conductive layer

Methodology Applied
Scientific EffectElectrical conductivity change: Conduction (electrical)

Data Source

PatentUS10761051B2Molecular detection apparatus and molecular detection method
Publication Date: 2020.09.01 KK TOSHIBA
  • US10761051B2 patent drawing
  • US10761051B2 patent drawing
  • US10761051B2 patent drawing

AI summary

A molecular detection apparatus according to an arrangement includes: a collection unit collecting a detection target gas containing a molecule to be detected; a detector including a detection cell that has an organic probe provided in a sensor unit, the organic probe capturing the collected molecule, and a discriminator discriminating the molecule by a detection signal generated by the molecule being captured by the organic probe of the detection cell. The detection cell has the organic probe including a dicyanovinyl structure or a coumarin structure.