Organic Semiconductor Composition for OLED Stability

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Solution Overview

Problem

There is a need for an organic semiconductor layer that enhances electron mobility and electrochemical stability to improve the performance and longevity of organic light-emitting diodes, particularly for large-size flat panel displays, while maintaining high brightness and extended lifespan at higher current densities.

Innovation Solution

A composition comprising specific compounds and organic metal complexes, where the compounds are formulated to optimize electron transport characteristics, including the use of alkali, alkaline earth, or rare earth metals, and specific heteroaryl groups, to form an organic semiconductor layer with improved charge mobility and stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic semiconductor materials are used, then device structure can be maintained, but electron mobility and electrochemical stability are insufficient

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidelectron mobility
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent employs composite organic semiconductor materials comprising multiple components with complementary functions. The composite structure combines materials with high electron mobility characteristics with materials providing electrochemical stability, achieving synergistic effects that resolve the contradiction between mobility and stability requirements.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies key parameters of organic semiconductor materials including molecular weight, glass transition temperature, and chemical composition to simultaneously improve electron mobility and electrochemical stability. By optimizing these parameters within specific ranges, the material achieves enhanced performance in both mobility and stability without compromising the other.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If higher current density is applied to increase brightness, then luminance efficiency improves, but device lifetime decreases

Engineering Contradiction:
ImprovebrightnessVSAvoiddevice lifetime
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent incorporates stabilizing additives and optimized material compositions that preemptively protect the device against degradation when operated at high current densities. These materials cushion the impact of high current stress before it causes damage, enabling sustained high brightness operation without premature failure.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The patent adjusts operational parameters including current density thresholds and material properties to enable high brightness operation. By changing material parameters such as electrochemical stability and charge transport characteristics, the device can sustain higher current densities for extended periods without degradation.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If organic semiconductor layer composition is optimized for electron mobility, then charge transport improves, but manufacturing complexity increases

Engineering Contradiction:
Improvecharge mobilityVSAvoidmaterial composition complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent establishes specific parameter ranges for organic semiconductor materials including molecular weight, glass transition temperature, and compositional ratios. By optimizing these parameters within defined ranges, high charge mobility is achieved through systematic material design rather than complex multi-component systems, simplifying manufacturing while maintaining performance.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly enhances the lifetime of organic light-emitting diodes while maintaining operating voltage, achieving superior performance over existing technologies, with improved luminance efficiency and stability, and allowing for mass production with controlled deposition rates.

Implementation Method 1

the composition can have strong electron transport characteristics to increase charge mobility

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

development of an organic semiconductor layer being capable of increasing electron mobility and simultaneously increasing electrochemical stability

Methodology Applied
Scientific EffectElectrochemical stability:

Data Source

PatentEP3689867B1Composition, organic semiconductor layer and electronic device
Publication Date: 2021.12.15 NOVALED GMBH
  • EP3689867B1 patent drawingFigure 1~3
  • EP3689867B1 patent drawingFigure 4~6
  • EP3689867B1 patent drawing

AI summary

The present invention relates to a composition, in particular to an organic semiconductor layer comprising a composition, suitable for use as an organic semiconductor layer for electronic devices, and a method of manufacturing the same, wherein the composition comprises: a) a compound of formula 1: and b) at least one organic metal complex, wherein the metal of the organic metal complex is selected from the group comprising alkali, alkaline earth or rare earth metal.