Organic Semiconductor Compound for OLED Electron Transport

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Solution Overview

Problem

Current organic semiconductor materials for OLEDs face challenges in achieving high electron mobility, electrochemical stability, and extended lifespan at higher current densities, leading to limitations in efficiency and lifetime, particularly at low operating voltages.

Innovation Solution

A compound of formula 1 is introduced, comprising a conjugated system with specific aromatic rings and substituents, which can be used as an electron transport layer to enhance charge injection, mobility, and stability, thereby improving luminance efficiency and voltage characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic semiconductor materials are used, then the device structure is simple, but electron mobility and electrochemical stability are insufficient

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidcompound structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite organic semiconductor materials comprising multiple functional units (electron-transporting units, aromatic units, and substituent units) combined in specific molecular structures. This composite approach enables simultaneous achievement of high electron mobility and electrochemical stability by integrating complementary functional properties within a single material system, resolving the contradiction between reliability improvement and structural complexity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention applies local quality by designing specific functional units with distinct roles within the overall molecular structure. Electron-transporting units provide high electron mobility, aromatic units contribute to electrochemical stability, and substituent units adjust solubility and processing properties. Each local region of the molecule is optimized for its specific function, enabling the material to achieve multiple performance targets simultaneously.

Inventive Principle:
Principle #3Local quality

2Productivity

If higher current density is applied to increase brightness, then luminance efficiency improves, but device lifetime decreases

Engineering Contradiction:
Improveluminance efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent utilizes parameter changes by systematically varying molecular structure parameters (conjugation length, aromatic ring substitution patterns, electron-transporting group types) to optimize the balance between luminance efficiency and device lifetime. The compounds are designed with specific LUMO energy levels and HOMO-LUMO gaps that enable efficient electron transport at moderate current densities while maintaining stability against degradation, thus achieving both high productivity and extended duration of action.

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If operating voltage is reduced to lower power consumption, then energy efficiency improves, but charge injection and electron mobility are compromised

Engineering Contradiction:
Improvepower consumptionVSAvoidelectron mobility
Core Design Contradiction:
Use of energy by moving objectVSSpeed

Solution Approach 1:

The patent replaces traditional high-voltage-driven electron transport mechanisms with materials that exhibit intrinsic high electron mobility through molecular design. The organic semiconductor compounds are engineered with extended conjugation systems and specific electron-transporting units that facilitate rapid electron delocalization and hopping, enabling efficient charge transport at reduced operating voltages. This substitution of material properties for operational parameters achieves low power consumption without sacrificing electron mobility.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Data Source

PatentEP3643720B1Organic compounds, organic semiconductor layer and organic electronic device
Publication Date: 2021.09.29 NOVALED GMBH
  • EP3643720B1 patent drawingFigure 1~2
  • EP3643720B1 patent drawingFigure 3
  • EP3643720B1 patent drawingFigure 4

AI summary

The present invention relates to a compound according to formula 1: suitable for use as a layer material for electronic devices, and to an organic semiconductor layer comprising at least one compound according to formula 1, as well as to an organic electronic device comprising at least one organic semiconductor layer, and a method of manufacturing the same.