Organic Semiconductor Layer for OLED Electron Transport

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Solution Overview

Problem

Current organic semiconductor layers in OLEDs face challenges in achieving balanced electron mobility and electrochemical stability, leading to limited lifespan and increased operating voltage, which affects the performance and power consumption of large-size flat panel displays and mobile devices.

Innovation Solution

Incorporating a metal dopant and a specific compound represented by Formula (I) into the organic semiconductor layer, which includes aryl and heteroaryl groups, to enhance electron transport characteristics and stability, thereby improving charge mobility and reducing operating voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional organic semiconductor materials are used in the electron transport layer, then the device structure is simple, but the electron mobility is insufficient and electrochemical stability is poor

Engineering Contradiction:
Improveelectrochemical stabilityVSAvoidmaterial composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs composite materials by combining a specific organic compound (Formula I) with a metal dopant in the electron transport layer. This composite approach enables simultaneous achievement of high electron mobility and electrochemical stability, resolving the contradiction between reliability and material complexity. The synergistic interaction between the host compound and metal dopant creates enhanced performance that neither material could achieve alone.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes key parameters including the molecular structure of the organic compound (Formula I), the type and concentration of metal dopant, and the weight ratio between host and dopant. By systematically adjusting these parameters, the invention achieves optimal balance between electron mobility and electrochemical stability, transforming the trade-off into a optimized performance state.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If conventional organic semiconductor materials are used, then the manufacturing process is simple, but the operating voltage is high and power consumption is increased

Engineering Contradiction:
Improvepower consumptionVSAvoidmanufacturing simplicity
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

The patent reduces operating voltage and power consumption by optimizing molecular parameters of the organic compound (Formula I) and dopant concentration. The improved electron mobility from the composite material enables more efficient charge transport, reducing the voltage required for operation and thereby lowering power consumption without complicating the manufacturing process.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes vacuum deposition techniques to form the electron transport layer, copying established manufacturing processes from conventional OLED fabrication. This approach maintains ease of manufacture while achieving improved electrical characteristics through the optimized material composition.

Inventive Principle:
Principle #26Copying

3Duration of action of moving object

If conventional organic semiconductor materials are used, then the device structure is simple, but the luminance efficiency is poor and lifespan is limited

Engineering Contradiction:
Improvedevice lifespanVSAvoidelectron transport layer composition
Core Design Contradiction:
Duration of action of moving objectVSDevice complexity

Solution Approach 1:

The patent extends device lifespan by creating a composite electron transport layer combining compound (Formula I) with metal dopant. This composite structure provides superior electrochemical stability and resistance to degradation under operating conditions, significantly extending device lifetime compared to conventional single-material layers.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent employs small amounts of metal dopant (typically 0.1-10 wt%) in the electron transport layer, using a minimal concentration of the active component to achieve maximum benefit. This approach extends device lifespan without requiring large quantities of expensive or complex materials.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution results in improved luminance efficiency, voltage characteristics, and extended lifespan of OLEDs, while maintaining current efficiency and reducing power consumption, particularly beneficial for mobile display devices.

Implementation Method 1

Incorporating a metal dopant and a specific compound represented by Formula (I) into the organic semiconductor layer, which includes aryl and heteroaryl groups, to enhance electron transport characteristics and stability, thereby improving charge mobility

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 2

When a voltage is applied to the anode and the cathode, holes injected from the anode move to the EML, via the HTL, and electrons injected from the cathode move to the EML, via the ETL. The holes and electrons recombine in the EML to generate excitons. When the excitons drop from an excited state to a ground state, light is emitted.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentEP3798213B1Organic semiconductor layer, organic electronic device comprising the same and compounds therefor
Publication Date: 2024.01.10 NOVALED GMBH
  • EP3798213B1 patent drawingFigure 1~2
  • EP3798213B1 patent drawingFigure 3
  • EP3798213B1 patent drawingFigure 4

AI summary

The present invention relates to an organic semiconductor layer and an organic electronic device comprising the same, wherein the organic electronic device comprises an anode, a cathode and at least one organic semiconductor layer, wherein the at least one organic semiconductor layer comprises: - a metal dopant, and - a compound represented by the following formula (I):