Organometallic Compound for Deep Blue OLED Emission

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan while maintaining deep blue light emission with specific spectral and color coordinates.

Innovation Solution

An organometallic compound represented by Formula 1, where M is Ir, Pt, Os, Ti, Zr, Hf, Eu, or Tm, and L1 and L2 are specific divalent and monovalent/ trivalent organic ligands, is incorporated into the emission layer of OLEDs, acting as a dopant and enhancing electrical characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoidenergy efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The patent modifies the chemical and electronic parameters of the emission layer by incorporating organometallic compounds with specific ligand structures (Formula 1 and Formula 2). These parameter changes in molecular structure and composition optimize the electrical characteristics, resulting in reduced driving voltage and improved energy efficiency of the OLED device.

Inventive Principle:
Principle #35Parameter changes

2Illumination intensity

If conventional emission layers are used, then basic light emission is achieved, but brightness and lifespan are insufficient

Engineering Contradiction:
ImprovebrightnessVSAvoidlifespan
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent employs composite organometallic compounds consisting of metal centers (Ir, Pt, Os, Ti, Zr, Hf, Eu, or Tm) combined with specifically designed organic ligands (Formula 1 and Formula 2). This composite material approach creates emission layer materials with superior optical and electrical properties, simultaneously enhancing brightness output and device operational lifespan.

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If standard organometallic compounds are used, then general light emission is achieved, but deep blue light emission with specific spectral characteristics is not attained

Engineering Contradiction:
Improvedeep blue light emissionVSAvoidspectral and color coordinates control
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The patent applies local quality by designing ligands with specific functional groups and structural features (Formula 1 and Formula 2) that are tailored to produce deep blue light emission. The localized chemical modifications in the ligand structure enable precise control over the emission spectrum and color coordinates, achieving the desired deep blue characteristics while maintaining manufacturing feasibility.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The OLEDs exhibit low driving voltage, high efficiency, high brightness, and long lifespan, with deep blue light emission within specified spectral and color coordinates, suitable for use in OLEDs.

Implementation Method 1

Holes provided from the anode may move toward the emission layer through the hole transport region, and electrons provided from the cathode may move toward the emission layer through the electron transport region. The holes and electrons are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS9812657B2Organometallic compound and organic light-emitting device including the same
Publication Date: 2017.11.07 SAMSUNG ELECTRONICS CO LTD
  • US9812657B2 patent drawing
  • US9812657B2 patent drawing
  • US9812657B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:M(L1)n1(L2)n2  Formula 1wherein in Formula 1, M, L1, L2, n1, and n2 are the same as described in the specification.