Organometallic Compound Emission Layer for Light-Emitting Devices

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Solution Overview

Problem

Current light-emitting devices face limitations in achieving high luminescence efficiency and low driving voltage characteristics, particularly in the emission layer where the balance of holes and electrons is not effectively managed.

Innovation Solution

Incorporating an organometallic compound represented by Formula 1 into the emission layer of the light-emitting device, which includes a host and a dopant, allowing for efficient energy transfer and balanced charge injection, thereby enhancing luminescence efficiency and reducing driving voltage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional emission layer materials are used, then device structure is simple, but luminescence efficiency is low and driving voltage is high

Engineering Contradiction:
Improveluminescence efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSUse of energy by stationary object

Solution Approach 1:

The emission layer employs a composite material system comprising a host material and a dopant material (organometallic compound). The host material provides the structural framework and charge transport pathways, while the dopant material (Formula 1) serves as the luminescent center. This composite approach enables efficient energy transfer from the host to the dopant, achieving high luminescence efficiency while maintaining balanced charge injection and reducing driving voltage requirements.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional emission layer materials are used, then device structure is simple, but charge balance between holes and electrons is poor

Engineering Contradiction:
Improvecharge balanceVSAvoidemission layer composition
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The emission layer is designed with distinct functional zones at the molecular level: the host material forms the continuous matrix responsible for charge transport, while the dopant molecules (Formula 1) are distributed throughout as discrete luminescent centers. This local differentiation allows the host to optimize charge balance by providing separate pathways for holes and electrons, while the dopant focuses on efficient radiative recombination, achieving excellent charge balance without excessive structural complexity.

Inventive Principle:
Principle #3Local quality

3Use of energy by moving object

If high luminescence efficiency is achieved through material optimization, then energy conversion is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveenergy conversion efficiencyVSAvoidmanufacturing process
Core Design Contradiction:
Use of energy by moving objectVSEase of manufacture

Solution Approach 1:

The organometallic compound (Formula 1) incorporates adjustable parameters including different metal centers (M1, M2 from groups including Pt, Pd, Ir, Ru), variable ligand types (ring CY1-CY4, Ar1, Ar2), and tunable substituent groups (R1-R4, R10a). These parameter variations allow optimization of luminescence efficiency, color emission, and charge balance without fundamentally changing the molecular architecture or manufacturing process. The consistent core structure across different parameter combinations simplifies manufacturing while enabling precise performance tuning.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the organometallic compound in the emission layer improves the luminescence efficiency and achieves high-efficiency, low-driving-voltage characteristics in the light-emitting device by effectively balancing hole and electron injection and emission.

Implementation Method 1

allowing for efficient energy transfer and balanced charge injection

Methodology Applied
Scientific EffectEnergy transfer:

Implementation Method 2

These excitons transition (decay or relax) from an excited state to a ground state to thereby generate light

Methodology Applied
Scientific EffectLuminescence: Luminescence

Implementation Method 3

balanced charge injection, thereby enhancing luminescence efficiency and reducing driving voltage

Methodology Applied
Scientific EffectCharge injection:

Data Source

PatentUS20240268215A1Light-emitting device including organometallic compound, electronic apparatus including the light-emitting device, and the organometallic compound
Publication Date: 2024.08.08 SAMSUNG DISPLAY CO LTD
  • US20240268215A1 patent drawing
  • US20240268215A1 patent drawing
  • US20240268215A1 patent drawing

AI summary

A light-emitting device includes a first electrode, a second electrode facing the first electrode; an interlayer between the first electrode and the second electrode, the interlayer including an emission layer; and an organometallic compound represented by Formula 1:wherein more details of Formula 1 are as described in the specification.