Organometallic Compound for OLED Emission Layer

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Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan while maintaining excellent color purity and quantum efficiency.

Innovation Solution

The development of an organometallic compound represented by Formula 1, which can be used as a dopant in the organic layer of OLEDs, improves electron transport characteristics and thermal stability, allowing for controlled emission wavelengths and extended device lifespan.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then device structure is simple, but driving voltage is high and efficiency is low

Engineering Contradiction:
Improvedriving voltageVSAvoiddevice structure
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The patent modifies the molecular structure parameters of the emission layer materials, specifically introducing a carbazole group and optimizing the HOMO-LUMO energy levels. This changes the electrical and optical parameters of the device, enabling lower driving voltage and higher efficiency without fundamentally altering the device structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials in the emission layer, combining a host material with a guest dopant material having specific molecular structures. This composite approach allows optimization of both charge transport and emission properties, achieving low driving voltage and high efficiency simultaneously.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional emission layers are used, then device manufacturing is simple, but luminescent efficiency is low

Engineering Contradiction:
Improveluminescent efficiencyVSAvoidemission layer fabrication
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent optimizes the local quality of the emission layer by carefully selecting and distributing specific functional groups (carbazole, electron transport groups) at molecular levels. This local optimization enhances luminescent efficiency while maintaining compatibility with conventional vacuum deposition manufacturing processes.

Inventive Principle:
Principle #3Local quality

3Duration of action of stationary object

If conventional organic layers are used, then device structure is simple, but lifespan is short

Engineering Contradiction:
Improvedevice lifespanVSAvoidorganic layer composition
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The patent replaces conventional short-living organic emission materials with newly synthesized organometallic compounds that have enhanced thermal and chemical stability. These new materials maintain the simplicity of organic layer fabrication while dramatically extending device lifespan through improved material durability.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Loss of energy

If conventional emission materials are used, then color purity is acceptable, but quantum efficiency is low

Engineering Contradiction:
Improvequantum efficiencyVSAvoidemission wavelength control
Core Design Contradiction:
Loss of energyVSManufacturing precision

Solution Approach 1:

The patent precisely adjusts the energy level parameters (HOMO, LUMO, triplet energy levels) of the emission materials to optimize quantum efficiency. By controlling the energy level alignment between host and guest materials, the patent achieves high quantum efficiency while maintaining excellent color purity and emission wavelength control.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organometallic compound enhances luminescent efficiency, achieves low driving voltage, high quantum efficiency, and maintains excellent color purity, leading to OLEDs with improved performance and longevity.

Implementation Method 1

Holes and electrons recombine in the emission layer to produce excitons. These excitons transit from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

The organometallic compound improves electron transport characteristics in the organic layer

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

These excitons transit from an excited state to a ground state, thereby generating light

Methodology Applied
Scientific EffectLuminescence: Luminescence

Data Source

PatentUS11889750B2Organometallic compound, organic light-emitting device including the organometallic compound, and diagnostic composition including the organometallic compound
Publication Date: 2024.01.30 SAMSUNG ELECTRONICS CO LTD
  • US11889750B2 patent drawing
  • US11889750B2 patent drawing
  • US11889750B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:wherein in Formula 1, A1 to A4, M, and T1 to T3 are the same as described in the specification.