Organometallic Compound for OLED Driving Voltage and Efficiency

Solution Overview

Problem

Organic light-emitting devices (OLEDs) face challenges in achieving low driving voltage, high efficiency, high brightness, and long lifespan while maintaining high color purity.

Innovation Solution

The development of an organometallic compound represented by Formula 1, which includes iridium (Ir) and specific ligands, is used in the organic layer of OLEDs to balance charge transport and reduce emission wavelength shift, thereby enhancing device stability and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If conventional organic light-emitting devices are used, then basic light emission is achieved, but driving voltage is high and efficiency is low

Engineering Contradiction:
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent modifies the chemical and physical parameters of the emission layer by incorporating specific organometallic compounds with defined ligand structures (Formula 1-3). This changes the energy levels, HOMO-LUMO gaps, and charge transport properties of the material, enabling lower driving voltage and higher efficiency simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite organometallic compounds combining iridium or platinum centers with specific organic ligands containing electron-donating and electron-withdrawing groups. This composite structure enables both low driving voltage and high efficiency by balancing charge injection and recombination processes

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If high brightness is achieved, then luminance is improved, but device lifespan is reduced

Engineering Contradiction:
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent introduces ligands with specific local functional groups (electron-donating and electron-withdrawing groups at different positions) to create localized charge distribution. This local quality control reduces hot spot formation and thermal degradation at high brightness levels, extending device lifespan

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The organometallic compounds are designed with built-in protective features including stable metal centers (Ir, Pt) and robust ligand frameworks that prevent degradation before it occurs. This beforehand cushioning against chemical and thermal stress enables sustained high brightness operation

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Measurement precision

If color purity is enhanced, then emission quality is improved, but emission wavelength shifts occur

Engineering Contradiction:
Core Design Contradiction:
Measurement precisionVSStability of the object's composition

Solution Approach 1:

The patent employs ligand designs that provide electronic feedback stabilization to the metal center, maintaining consistent emission wavelengths. The specific arrangement of electron-donating and electron-withdrawing groups creates a balanced electronic environment that prevents wavelength drift while maintaining high color purity

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

By precisely controlling the chemical parameters of the ligands (substituent types, positions, and combinations), the patent tunes the emission wavelength and color purity while maintaining stability. The defined structural parameters in Formulae 1-3 ensure reproducible emission characteristics

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organometallic compound enables OLEDs to operate at low driving voltage with high efficiency, high brightness, and extended lifespan, while maintaining high color purity and stability.

Implementation Method 1

Holes provided from the anode may move toward the emission layer through the hole transport region, and electrons provided from the cathode may move toward the emission layer through the electron transport region. The holes and the electrons are recombined in the emission layer to produce excitons. These excitons change from an excited state to a ground state, thereby generating light.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10672995B2Organometallic compound and organic light-emitting device including the same
Publication Date: 2020.06.02
  • US10672995B2 patent drawing
  • US10672995B2 patent drawing
  • US10672995B2 patent drawing

AI summary

An organometallic compound represented by Formula 1:Ir(L1)n(L2)(3-n)  Formula 1wherein in Formula 1, L1, L2, and n are the same as described in the specification.